ISSN:
1042-7147
Keywords:
stacking
;
pyrido(3,2-f) (1,7)phenanthroline
;
phenanthroline
;
ATP
;
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
Notes:
The stability constants of the ternary mixed ligand complex Cu(pdphen) (ATP)2-, where pdphen is the planar ligand pyrido(3,2-f) (1,7)phenanthroline, were determined by potentiometric pH titration in water, and in 30 and 50% (v/v) aqueous dioxane solutions. It has been observed from this information that a stronger stacking interaction between pdphen and the base of ATP exists and decreases with decreasing solvent polarity, i.e. increasing amounts of dioxane in the solvent mixture.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
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