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  • 1
    Publication Date: 2023-08-29
    Description: Karst hydrosystems represent one of the largest global drinking water resources, but they are extremely vulnerable to pollution. Climate change, high population density, intensive industrial, and agricultural activities are the principal causes of deterioration, both in terms of quality and quantity, of these resources. Samples from 172 natural karst springs were collected in the whole territory of Greece. To identify any geogenic contamination and/or anthropogenic pollution, analyses of their chemical compositions, in terms of major ions and trace elements, were performed and compared to the EU limits for drinking water. Based on chloride content, the collected karst springs were divided into two groups: low-chloride (〈 100 mg L-1) and high-chloride content (〉 100 mg L-1). An additional group of springs with calcium-sulfate composition was recognised. Nitrate concentrations were always below the EU limit (50 mg L-1), although some springs presented elevated concentrations. High contents in terms of trace elements, such as B, Sr, As, and Pb, sometimes exceeding the limits, were rarely found. The Greek karst waters can still be considered a good quality resource both for human consumption and for agriculture. The main issues derive from seawater intrusion in the aquifers along the coasts. Moreover, the main anthropogenic pollutant is nitrate, found in higher concentrations mostly in the same coastal areas where human activities are concentrated. Finally, high levels of potentially harmful trace elements (e.g. As, Se) are very limited and of natural origin (geothermal activity, ore deposits, etc.).
    Description: Published
    Description: 11191
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: Greece ; Hydrogeochemistry ; trace elements ; water quality ; karst springs ; 03.04. Chemical and biological
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Limitation Availability
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  • 2
    Publication Date: 2023-08-29
    Description: Natural thermal and mineral waters are widely distributed along the Hellenic region and are related to the geodynamic regime of the country. The diverse lithological and tectonic settings they are found in reflect the great variability in their chemical and isotopic composition. The current study presents 276 (published and unpublished) trace element water data and discusses the sources and processes affecting the water by taking into consideration the framework of their geographic distribution. The dataset is divided in groups using temperature- and pH-related criteria. Results yield a wide range of concentrations, often related to the solubility properties of the individual elements and the factors impacting them (i.e. temperature, acidity, redox conditions and salinity). Many elements (e.g. alkalis, Ti, Sr, As and Tl) present a good correlation with temperature, which is in cases impacted by water rock interactions, while others (e.g. Be, Al, Cu, Se, Cd) exhibit either no relation or an inverse correlation with T possibly because they become oversaturated at higher temperatures in solid phases. A moderately constant inverse correlation is noticed for the vast majority of trace elements and pH, whereas no relationship between trace element concentrations and Eh was found. Seawater contamination and water-rock interaction seem to be the main natural processes that influence both salinity and elemental content. All in all, Greek thermomineral waters exceed occasionally the accepted limits representing in such cases serious harm to the environment and probably indirectly (through the water cycle) to human health.
    Description: Published
    Description: 78376–78393
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: Greece ; Hydrogeochemistry ; Mineral waters ; Natural contaminants ; Trace elements ; Water-rock interaction ; Thermal waters ; 03.04. Chemical and biological
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Limitation Availability
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