Description: Highlights • 3D seismic imaging of an entire landslide complex. • Shallow gas accumulation within and underneath Tuaheni Landslide Complex. • Imaging of a basal shear zone within a subaqueous landslide complex. Abstract The Hikurangi margin is an active continental margin east of New Zealand's North Island. It is well recognized as a seismically active zone and is known for the occurrence of free gas and gas hydrates within the shallow sediments. A variety of subaqueous landslides can be observed at the margin, including the Tuaheni Landslide Complex off Poverty Bay. This slide complex has been interpreted previously as a slowly creeping landform, as its morphology and internal deformation is comparable to terrestrial earthflows and rock glaciers. In 2014, we acquired a high-resolution 3D seismic volume covering major parts of the Tuaheni South landslide. The 3D data show a variety of fluid migration indicators, free gas accumulations and manifestations of the base of gas hydrate stability in the pre-slide sedimentary units and the lower unit of the landslide system. The data also show that the landslide system is composed of an upper and lower unit that are separated by an intra-debris negative-polarity reflection. Free gas accumulations directly beneath the landslide units suggest that the debris acts as a boundary for rising fluids and only few migration pathways to the intra-debris reflector are observed in the distal parts of the landslide. Deformation within the landslide's debris is focused in the upper landslide unit, and we interpret the intra-debris reflector as a basal shear zone or ‘glide plane’ upon which the debris has been remobilized. The origin of the intra-debris reflector is unclear, but we suggest it could be a relatively coarse-grained horizon that would be prone to fluid flow focusing and the development of excess fluid pressure. Our seismic study provides one of the most detailed examples of a subaqueous landslide system and reveals insights into the fluid flow system and potential basal shear zone development of the Tuaheni Landslide Complex.

Description: Highlights • Gas release from wells may counteract efforts to mitigate greenhouse gas emissions. • An approach for assessing methane release from marine decommissioned wells. • This gas release largely depends on the presence of shallow gas accumulations. • Methane release from hydrocarbon wells represents a major source in the North Sea. Abstract Hydrocarbon gas emissions from with decommissioned wells are an underreported source of greenhouse gas emissions in oil and gas provinces. The associated emissions may partly counteract efforts to mitigate greenhouse gas emissions from fossil fuel infrastructure. We have developed an approach for assessing methane leakage from marine decommissioned wells based on a combination of existing regional industrial seismic and newly acquired hydroacoustic water column imaging data from the Central North Sea. Here, we present hydroacoustic data which show that 28 out of 43 investigated wells release gas from the seafloor into the water column. This gas release largely depends on the presence of shallow gas accumulations and their distance to the wells. The released gas is likely primarily biogenic methane from shallow sources. In the upper 1,000 m below the seabed, gas migration is likely focused along drilling-induced fractures around the borehole or through non-sealing barriers. Combining available direct measurements for methane release from marine decommissioned wells with our leakage analysis suggests that gas release from investigated decommissioned hydrocarbon wells is a major source of methane in the North Sea (0.9-3.7 [95% confidence interval = 0.7-4.2] kt yr−1 of CH4 for 1,792 wells in the UK sector of the Central North Sea). This means hydrocarbon gas emissions associated with marine hydrocarbon wells are not significant for the global greenhouse gas budget, but have to be considered when compiling regional methane budgets.

Description: Volcanic island flank collapses have the potential to trigger devastating tsunamis threatening coastal communities and infrastructure. The 1888 sector collapse of Ritter Island, Papua New Guinea (in the following called Ritter) is the most voluminous volcanic island flank collapse in historic times. The associated tsunami had run-up heights of more than 20 m on the neighboring islands and reached settlements 600 km away from its source. This event provides an opportunity to advance our understanding of volcanic landslide-tsunami hazards. Here, we present a detailed reconstruction of the 1888 Ritter sector collapse based on high-resolution 2D and 3D seismic and bathymetric data covering the failed volcanic edifice and the associated mass-movement deposits. The 3D seismic data reveal that the catastrophic collapse of Ritter occurred in two phases: (1) Ritter was first affected by deep-seated, gradual spreading over a long time period, which is manifest in pronounced compressional deformation within the volcanic edifice and the adjacent seafloor sediments. A scoria cone at the foot of Ritter acted as a buttress, influencing the displacement and deformation of the western flank of the volcano and causing shearing within the volcanic edifice. (2) During the final, catastrophic phase of the collapse, about 2.4 km³ of Ritter disintegrated almost entirely and travelled as a highly energetic mass flow, which incised the underlying sediment. The irregular topography west of Ritter is a product of both compressional deformation and erosion. A crater-like depression underlying the recent volcanic cone and eyewitness accounts suggest that an explosion may have accompanied the catastrophic collapse. Our findings demonstrate that volcanic sector collapses may transform from slow gravitational deformation to catastrophic collapse. Understanding the processes involved in such a transformation is crucial for assessing the hazard potential of other volcanoes with slowly deforming flanks such as Mt. Etna or Kilauea.

Description: Highlights • Ritter Island's sector collapse provides an exemplar of volcanic tsunami hazards. • Deposit heterogeneity reflects erosion, secondary failure and a triggered eruption. • The volume of the distal deposit alone far exceeds the tsunamigenic failure. • A single catastrophic collapse led to stratigraphically complex distal deposits. • Accurate assessment of tsunami potential requires internal imaging and sampling. Abstract The current understanding of tsunamis generated by volcanic-island landslides is reliant on numerical models benchmarked against reconstructions of past events. As the largest historical event with timed tsunami observations, the 1888 sector collapse of Ritter Island, Papua New Guinea provides an outstanding opportunity to better understand the linked process of landslide emplacement and tsunami generation. Here, we use a combination of geophysical imaging, bathymetric mapping, seafloor observations and sampling to demonstrate that the Ritter landslide deposits are spatially and stratigraphically heterogeneous, reflecting a complex evolution of mass-flow processes. The primary landslide mass was dominated by well-bedded scoriaceous deposits, which rapidly disintegrated to form an erosive volcaniclastic flow that incised the substrate over much of its pathway. The major proportion of this initial flow is inferred to have been deposited up to 80 km from Ritter. The initial flow was followed by secondary failure of seafloor sediment, over 40 km from Ritter. The most distal part of the 1888 deposit has parallel internal boundaries, suggesting that multiple discrete units were deposited by a series of mass-flow processes initiated by the primary collapse. The last of these flows was derived from a submarine eruption triggered by the collapse. This syn-collapse eruption deposit is compositionally distinct from pre- and post-collapse eruptive products, suggesting that the collapse immediately destabilised the underlying magma reservoir. Subsequent eruptions have been fed by a modified plumbing system, constructing a submarine volcanic cone within the collapse scar through at least six post-collapse eruptions. Our results show that the initial tsunami-generating landslide at Ritter generated a stratigraphically complex set of deposits with a total volume that is several times larger than the initial failure. Given the potential for such complexity, there is no simple relationship between the volume of the tsunamigenic phase of a volcanic-island landslide and the final deposit volume, and deposit area or run-out cannot be used to infer primary landslide magnitude. The tsunamigenic potential of prehistoric sector-collapse deposits cannot, therefore, be assessed simply from surface mapping, but requires internal geophysical imaging and direct sampling to reconstruct the event.

Description: Highlights • Unprecedented dense coverage of ocean-bottom seismometer data reveals seismic velocity variations within a vertical fluid pathway. • There are zones of both positive (faster) and negative (slower) velocity within the fluid pathway compared to the background formation velocities. • Velocity reductions are related to free gas in the fluid pathway, while the reason for velocity increases is unclear but potentially caused by cementation. Abstract Subsurface CO2 storage is a key strategy to reduce greenhouse gas emission, but leakage of CO2 along natural fluid pathways may affect storage formation integrity. However, the internal structure and the physical properties of these focused fluid conduits are poorly understood. Here, we present a three-dimensional seismic velocity model of an active fluid conduit beneath the Scanner Pockmark in the Central North Sea, derived from ocean-bottom seismometer data. We show that the conduit, which manifests as a pipe structure in seismic data, is separated into two parts. The upper part, extending to 260 m depth, i.e. 110 m below the seafloor, is characterised by seismic velocities up to 100 m/s slower than the surrounding strata. The deeper part is characterized by a 50 m/s seismic velocity increase compared to background velocity. We suggest that the upper part of the pipe structure represents a network of open fractures, partly filled with free gas, while the reason for the velocity increase in the lower part remains speculative. These observations suggest that active pipes can be internally heterogeneous with some intervals probably being open fluid pathways and other intervals being closed. This study highlights the complexity in evaluating focused fluid conduits and the necessity of their detailed assessment when selecting CO2 storage sites.

Description: We present porosity and free gas estimations and their uncertainties at anactive methane venting site in the UK sector of the North Sea. In the Scan-ner Pockmark area in about 150m water depth, we performed a multi-disciplinary experiment to investigate the physical properties of fluid flowstructures within unconsolidated glaciomarine sediments. Here we focus onthe towed controlled source electromagnetic (CSEM) data analysis with con-straints from seismic reflection and core logging data. Inferred backgroundresistivity values vary between 0.6–1 Ωm at the surface and 1.9–2.4 Ωm at150 mbsf. We calibrate Archie’s parameters with measurements on cores, andestimate porosities of about 50±10% at the seafloor decreasing to 25±3% at 150 mbsf which matches variations expected for mechanical compaction ofclay rich sediments. High reflectivity in seismic reflection data is consistentwith the existence of a gas pocket. A synthetic study of varying gas contentin this gas pocket shows that at least 33±8% of free gas are required to causea distinct CSEM data anomaly. Real data inversions with seismic constraintssupport the presence of up to 34±14% free gas in a 30–40 m thick gas pocketunderneath the pockmark within the stratigraphic highs of a till layer abovethe glacial unconformity in the Aberdeen Ground Formation.

Description: Highlights • An artificial CO2 release demonstrated MMV techniques for offshore CCS. • Detection of leakage was demonstrated using acoustic, chemical and physical approaches. • Attribution of leakage was proved possible using artificial and natural tracer compounds. • Leakage quantification was possible using approaches not previously applied to CCS studies. • Non-catastrophic leaks were detected at levels below those that would cause environmental harm. Carbon capture and storage is a key mitigation strategy proposed for keeping the global temperature rise below 1.5 °C. Offshore storage can provide up to 13% of the global CO2 reduction required to achieve the Intergovernmental Panel on Climate Change goals. The public must be assured that potential leakages from storage reservoirs can be detected and that therefore the CO2 is safely contained. We conducted a controlled release of 675 kg CO2 within sediments at 120 m water depth, to simulate a leak and test novel detection, quantification and attribution approaches. We show that even at a very low release rate (6 kg day−1), CO2 can be detected within sediments and in the water column. Alongside detection we show the fluxes of both dissolved and gaseous CO2 can be quantified. The CO2 source was verified using natural and added tracers. The experiment demonstrates that existing technologies and techniques can detect, attribute and quantify any escape of CO2 from sub-seabed reservoirs as required for public assurance, regulatory oversight and emissions trading schemes.

Description: Carbon capture and storage (CCS) is a key technology to reduce carbon dioxide (CO2) emissions from industrial processes in a feasible, substantial, and timely manner. For geological CO2 storage to be safe, reliable, and accepted by society, robust strategies for CO2 leakage detection, quantification and management are crucial. The STEMM-CCS (Strategies for Environmental Monitoring of Marine Carbon Capture and Storage) project aimed to provide techniques and understanding to enable and inform cost-effective monitoring of CCS sites in the marine environment. A controlled CO2 release experiment was carried out in the central North Sea, designed to mimic an unintended emission of CO2 from a subsurface CO2 storage site to the seafloor. A total of 675 kg of CO2 were released into the shallow sediments (~3 m 49 below seafloor), at flow rates between 6 and 143 kg/d. A combination of novel techniques, adapted versions of existing techniques, and well-proven standard techniques were used to detect, characterise and quantify gaseous and dissolved CO2 in the sediments and the overlying seawater. This paper provides an overview of this ambitious field experiment. We describe the preparatory work prior to the release experiment, the experimental layout and procedures, the methods tested, and summarise the main results and the lessons learnt.

Description: Evaluation of seismic reflection data has identified the presence of fluid escape structures cross-cutting overburden stratigraphy within sedimentary basins globally. Seismically-imaged chimneys/pipes are considered to be possible pathways for fluid flow, which may hydraulically connect deeper strata to the seabed. These fluid migration pathways through the overburden must be constrained to enable secure, long-term subsurface carbon dioxide (CO2) storage. We have investigated a site of natural active fluid escape in the North Sea, the Scanner Pockmark Complex, to determine the physical characteristics of focused fluid conduits, and how they control fluid flow. Here we show that a multi-scale, multi disciplinary experimental approach is required for complete characterisation of fluid escape structures. Geophysical techniques are necessary to resolve fracture geometry and subsurface structure (e.g., multifrequency seismics) and physical parameters of sediments (e.g., controlled source electromagnetics) across length scales (m to km). At smaller (mm to cm) scales, sediment cores were sampled directly and their physical and chemical properties assessed using laboratory-based methods. Numerical modelling approaches bridge the resolution gap, though their validity is dependent on calibration and constraint from field and laboratory experimental data. Further, time-lapse seismic and acoustic methods capable of resolving temporal changes are key for determining fluid flux. Future optimisation of experiment resource use may be facilitated by the installation of permanent seabed infrastructure, and replacement of manual data processing with automated workflows. This study can be used to inform measurement, monitoring and verification workflows that will assist policymaking, regulation, and best practice for CO2 subsurface storage operations.

Description: Fluid-escape structures within sedimentary basins permit pressure-driven focused fluid flow through inter-connected faults, fractures and sediment. Seismically-imaged chimneys are recognised as fluid migration pathways which cross-cut overburden stratigraphy, hydraulically connecting deeper strata with the seafloor. However, the geological processes in the sedimentary overburden which control the mechanisms of genesis and temporal evolution require improved understanding. We integrate high resolution 2D and 3D seismic reflection data with sediment core data to characterise a natural, active site of seafloor methane venting in the UK North Sea and Witch Ground Basin, the Scanner pockmark complex. A regional assessment of shallow gas distribution presents direct evidence of active and palaeo-fluid migration pathways which terminate at the seabed pockmarks. We show that these pockmarks are fed from a methane gas reservoir located at 70 metres below the seafloor. We find that the shallow reservoir is a glacial outwash fan, that is laterally sealed by glacial tunnel valleys. Overpressure generation leading to chimney and pockmark genesis is directly controlled by the shallow geological and glaciogenic setting. Once formed, pockmarks act as drainage cells for the underlying gas accumulations. Fluid flow occurs through gas chimneys, comprised of a sub-vertical gas-filled fracture zone. Our findings provide an improved understanding of focused fluid flow and pockmark formation within the sediment overburden, which can be applied to subsurface geohazard assessment and geological storage of CO2.