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  • 1
    ISSN: 1520-6882
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Journal of the American Chemical Society 109 (1987), S. 4780-4786 
    ISSN: 1520-5126
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Oxford UK : Blackwell Science Ltd
    Sedimentology 46 (1999), S. 0 
    ISSN: 1365-3091
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Sedimentology 44 (1997), S. 0 
    ISSN: 1365-3091
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Rimming the outer shelf of Grand Cayman is a submerged, 87 km long shelf-edge reef that rises to within 12 m of mean sea level. It consists of an array of coral-armoured buttresses aligned perpendicular to shore and separated by steep-sided sediment-floored canyons. Individual buttresses have a diverse coral-dominated biota and consist of three architectural elements: a shield-like front wall colonized by platy corals, a dome-shaped crown colonized by head corals, and a shoreward-projecting spur covered by varying amounts of branching coral. Buttresses are commonly fronted by coral pinnacles that, in some areas, have amalgamated with buttress walls to produce pinnacle-and-arch structures.As margin orientation changes, shelf-edge-reef architecture shows systematic variations that are consistent with changes in fetch and height of hurricane waves. Along margins exposed to fully developed storm waves, shelf-edge-reef buttresses are deep, have large amplitudes, and are dominated by robust head corals. These characteristics are consistent with hurricane-induced pruning of branching corals and the flushing of significant quantities of sand from buttress canyons by return flows. Along margins impacted by fetch-limited storm waves, reef buttresses are shallower, have intermediate-amplitudes, and have a significantly higher proportion of branching corals. These characteristics are consistent with less coral pruning and sand flushing by weaker hurricane waves. Along margins fully protected from storm waves, the buttresses-canyon architecture of the shelf-edge reef breaks down producing a series of shallow, undulating, branching-coral-dominated ridges that merge laterally into an unbroken belt of coral. These characteristics correspond with negligible amounts of pruning and flushing during hurricanes.In addition to differences between margins, local intra-marginal changes in shelf-edge reef architecture are consistent with changes in the angle of hurricane-wave approach. Open sections of the shelf-edge reef, which face directly into storm waves, are pruned of branching corals and the fragments swept back onto the shelf producing extensive spurs. By contrast, on more sheltered, obliquely orientated sections, storm-waves sweep debris along and off shelf producing little or no spur development. Instead, the debris shed seawards accumulates in front of the buttress walls and initiates the development of coral pinnacles.Over time, repeated buttress pruning and canyon flushing during hurricanes not only controls reef architecture but may also influence accretion patterns. Vertical accretion is limited by the effective depth of storm-wave fragmentation. Once this hurricane-accretion threshold is reached the reef moves into a shedding phase and accretes laterally via pinnacle growth, amalgamation, and infilling. Consequently, the reef steps out over its own debris in a kind of balancing act between lateral growth and slope failure — a pattern widely recognized in ancient reefs.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Sedimentology 44 (1997), S. 0 
    ISSN: 1365-3091
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Siliceous oncoids, up to 4 cm in diameter, are common on the laterally extensive sinter aprons that surround the spectacular geysers and hot springs at El Tatio in northern Chile. Many of these complex oncoids developed close to geyser and spring vents that discharge boiling water. Internally the oncoids, which are composed of precipitated amorphous silica, are formed of complex arrays of spicules and concentric laminae as well as detrital volcanic grains. Spicular growth is dominant in most examples. The formation and growth of the spicules and concentric laminae were mediated by a microbial community which included filamentous microbes, mucus, and possibly bacteria. The microbes and mucus were silicified by replacement and encrustation. In some laminae the filamentous microbes lay parallel to the growth surface; in other laminae most filaments forming the thin mats were suberect. Amorphous silica precipitated between the filaments occluded porosity and commonly disguised the microbial fabric.The oncoids grew on the proximal sinter aprons around the geyser vents and hot spring pools. Most growth took place subaerially with the silica delivered to the precipitation sites by splashing water from the geysers and/or periodic shallow flooding of the discharge aprons. Unlike silica oncoids at other geothermal sites, vertical growth of oncoids that formed in some rimstone pools was not limited by water depth.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Sedimentology 43 (1996), S. 0 
    ISSN: 1365-3091
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Pseudohexagonal aragonite crystals are common components in some hot-spring travertines at Chemurkeu on the western shore of Lake Bogoria, Kenya. Beds, lenses and pods of aragonite crystals are intercalated with beds of white non-crystallographic calcite dendrites. The pseudohexagonal aragonite crystals, which are up to 4 cm long and 4 mm wide, are formed of nested skeletal crystals. Each skeletal crystal is formed of cyclical twinned crystals that are constructed of stacked subcrystals. The latter are inclined at a consistent angle of 40° to the long axis of the pseudohexagonal aragonite crystal. Intense competition for space during growth modified the crystal morphology with the result that many of the pseudohexagonal crystals are distorted. Intercrystalline and intracrystalline pores are filled or partly filled by epitaxial aragonite overgrowths and/or reticulate microbial coatings that have a high concentration of Si and Mg. In places, this extracellular mucus induced etching of the underlying aragonite crystal.Today the hot (T〉95 °C) Na-HCO3-Cl spring waters at Chemurkeu have a salinity of 5–6 g L−1 TDS, a pH of 8·1–9·1, Ca2+ concentrations of 〈2 mg L−1 and Mg2+ concentrations of 〈0·7 mg L−1, The springs of the Lake Bogoria Geothermal Field are fed by a shallow aquifer (T∼100 °C) and a deeper aquifer (T∼170 °C). Springs at Chemurkeu derive from meteoric groundwater, lake water and condensed steam, and are fed mainly from the shallow thermal aquifer. Much of the aragonite may have formed when the spring waters contained more dissolved Ca2+ than today, possibly under more humid conditions during the Holocene.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Oxford UK : Blackwell Science Ltd, UK
    Sedimentology 45 (1998), S. 0 
    ISSN: 1365-3091
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Foraminifera can be used to determine the source(s) of carbonate sediment and the directions of sediment transport in shallow, coastal lagoons such as Frank Sound on the south-central coast of Grand Cayman. These determinations, based on the distribution of foraminiferal assemblages and ‘tracer species’ (numerically abundant species that live in known physiographic units and/or ecological conditions), show that the lagoonal sediments are a mixture of grains that originated in the lagoon and forereef. The variable proportions of these foraminifera throughout the lagoon reflects the dynamic processes that control lagoonal sedimentation. Amphistegina gibbosa, Discorbis rosea, and Asterigerina carinata lived in the forereef environment. The fact that these ‘tracer species’ are found throughout Frank Sound and in the beach sands, shows that they were transported across the reef crest and the lagoon. Abrasion-resistant Archaias angulatus, a‘tracer species’ indicative of a lagoonal setting, forms up to 50% of foraminiferal assemblages found in the lagoonal sediments. Preferential winnowing of small tests from these populations indicates sorting under high energy conditions. The vertical distribution of the forereef and lagoonal foraminifera in the sediment blanket that covers the floor of Frank Sound indicates that these processes are temporally persistent.Transportation of forereef foraminifera into and around the lagoon and sorting of the lagoonal foraminifera cannot take place under ‘normal’ conditions when the tranquil lagoon is characterized by weak currents. Storms and/or hurricanes, however, generate short-lived high-energy events that can move and sort the sediment and foraminifera. At the height of a storm, water and sediment are moved over the reef and then piled and held onshore by the onshore winds and the constant flow of water over the reef and across the lagoon. These currents can mix some of the lagoonal and forereef sediments. As a storm wanes, however, the ‘piled water’ flows offshore via strong rip currents that pass into the ocean through the channels which transect the reef. These currents winnow and/or strip sediment from the lagoon and may transport lagoonal sediments into the forereef area. As a result, residual lagoonal sediment is commonly characterized by larger and abrasion-resistant foraminifera.
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  • 8
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Sedimentology 43 (1996), S. 0 
    ISSN: 1365-3091
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Sedimentology 42 (1995), S. 0 
    ISSN: 1365-3091
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Sedimentology 36 (1989), S. 0 
    ISSN: 1365-3091
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Type of Medium: Electronic Resource
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