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  • 2015-2019  (25)
  • 2010-2014  (54)
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  • 1
    Online Resource
    Online Resource
    Reconstruction of the water mass circulation patterns in the Labrador Sea based on radiogenic isotopes and alkenone composition from the present day up to the Late Quaternary (35 kyrs) (2016)
    Kiel
    Details Availability
    Keywords: Hochschulschrift ; Labradorsee ; Oberflächenwasser ; Meeresströmung
    Type of Medium: Online Resource
    Pages: Online-Ressource (213 Seiten = 8 MB) , Diagramme, Karten
    URL: http://oceanrep.geomar.de/35354/
    DDC: 550
    Language: English
    Note: Zusammenfassung in deutscher und englischer Sprache
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  • 2
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    The acceleration of oceanic denitrification during deglacial warming (2013)
    Nature Publishing Group
    In:  Nature Geoscience, 6 (7). pp. 579-584.
    Details
    Publication Date: 2019-09-23
    Description: Over much of the ocean’s surface, productivity and growth are limited by a scarcity of bioavailable nitrogen. Sedimentary δ15N records spanning the last deglaciation suggest marked shifts in the nitrogen cycle during this time, but the quantification of these changes has been hindered by the complexity of nitrogen isotope cycling. Here we present a database of δ15N in sediments throughout the world’s oceans, including 2,329 modern seafloor samples, and 76 timeseries spanning the past 30,000 years. We show that the δ15N values of modern seafloor sediments are consistent with values predicted by our knowledge of nitrogen cycling in the water column. Despite many local deglacial changes, the globally averaged δ15N values of sinking organic matter were similar during the Last Glacial Maximum and Early Holocene. Considering the global isotopic mass balance, we explain these observations with the following deglacial history of nitrogen inventory processes. During the Last Glacial Maximum, the nitrogen cycle was near steady state. During the deglaciation, denitrification in the pelagic water column accelerated. The flooding of continental shelves subsequently increased denitrification at the seafloor, and denitrification reached near steady-state conditions again in the Early Holocene. We use a recent parameterization of seafloor denitrification to estimate a 30–120% increase in benthic denitrification between 15,000 and 8,000 years ago. Based on the similarity of globally averaged δ15N values during the Last Glacial Maximum and Early Holocene, we infer that pelagic denitrification must have increased by a similar amount between the two steady states.
    Type: Article , PeerReviewed
    Format: text
    Format: text
    DOI: 10.1038/ngeo1832
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    OceanRep: Article in a Scientific Journal - peer-reviewed
  • 3
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    Salinity control on Na incorporation into calcite tests of the planktonic foraminifera Trilobatus sacculifer – Evidence from culture experiments and surface sediments (2018)
    Copernicus Publications (EGU)
    In:  Biogeosciences (BG), 15 (20). pp. 5991-6018.
    Details
    Publication Date: 2021-03-18
    Description: The quantitative reconstruction of past seawater salinity has yet to be achieved and the search for a direct and independent salinity proxy is ongoing. Recent culture and field studies show a significant positive correlation of Na/Ca with salinity in benthic and planktonic foraminiferal calcite. For accurate paleoceanographic reconstructions, consistent and reliable calibrations are necessary, which are still missing. In order to assess the reliability of foraminiferal Na/Ca as a direct proxy for seawater salinity, this study presents electron microprobe Na/Ca data, measured on cultured specimens of Trilobatus sacculifer. The culture experiments were conducted over a wide salinity range of 26 to 45, while temperature was kept constant. To further understand potential controlling factors of Na incorporation, measurements were also performed on foraminifera cultured at various temperatures in the range of 19.5 °C to 29.5 °C under constant salinity conditions. Foraminiferal Na/Ca ratios positively correlate with seawater salinity (Na/Caforam = 0.97 + 0.115 ⋅ Salinity, R = 0.97, p 〈 0.005). Temperature on the other hand exhibits no statistically significant relationship with Na/Ca ratios indicating salinity to be the dominant factor controlling Na incorporation. The culturing results are corroborated by measurements on T. sacculifer from Caribbean and Gulf of Guinea surface sediments. In conclusion, planktonic foraminiferal Na/Ca can be applied as a reliable proxy for reconstructing sea surface salinities, albeit species-specific calibrations might be necessary.
    Type: Article , PeerReviewed
    Format: text
    DOI: 10.5194/bg-15-5991-2018
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    OceanRep: Article in a Scientific Journal - peer-reviewed
  • 4
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    Water mass circulation and weathering inputs in the Labrador Sea based on coupled Hf–Nd isotope compositions and rare earth element distributions (2017)
    Elsevier
    In:  Geochimica et Cosmochimica Acta, 199 . pp. 164-184.
    Details
    Publication Date: 2020-02-06
    Description: The Labrador Sea is one of the key areas for deep water formation driving the Atlantic thermohaline circulation and thus plays an important role in Northern Hemisphere climatic fluctuations. In order to better constrain the overturning processes and the origins of the distinct water masses, combined dissolved Hf–Nd isotopic compositions and rare earth element (REE) distribution patterns were obtained from four water depth profiles along a section across the Labrador Sea. These were complemented by one surface sample off the southern tip of Greenland, three shallow water samples off the coast of Newfoundland, and two deep water samples off Nova Scotia. Although light REEs are markedly enriched in the surface waters off the coast of Newfoundland compared to north Atlantic waters, the REE concentration profiles are essentially invariant throughout the water column across the Labrador Sea. The hafnium concentrations of surface waters exhibit a narrow range between 0.6 and 1 pmol/kg but are not significantly higher than at depth. Neodymium isotope signatures (ɛNd) vary from unradiogenic values between −16.8 and −14.9 at the surface to more radiogenic values near −11.0 at the bottom of the Labrador Sea mainly reflecting the advection of the Denmark Strait Overflow Water and North East Atlantic Deep Water, the signatures of which are influenced by weathering contributions from Icelandic basalts. Unlike Nd, water column radiogenic Hf isotope signatures (ɛHf) are more variable representing diverse weathering inputs from the surrounding landmasses. The least radiogenic seawater ɛHf signatures (up to −11.7) are found in surface waters close to Greenland and near the Canadian margin. This reflects the influence of recirculating Irminger Current Waters, which are affected by highly unradiogenic inputs from Greenland. A three to four ɛHf unit difference is observed between Denmark Strait Overflow Water (ɛHf ∼ −4) and North East Atlantic Deep Water (ɛHf ∼ −0.1), although their source waters have essentially the same ɛNd signature. This most likely reflects different weathering signals of hafnium delivered to Denmark Strait Overflow Water and North East Atlantic Deep Water (incongruent weathering of old rocks from Greenland versus basaltic rocks from Iceland). In addition, the ɛHf data resolve two layers within the main body of Labrador Sea Water not visible in the ɛNd distribution, which are shallow Labrador Sea Water (ɛHf ∼ −2) and deep Labrador Sea Water (ɛHf ∼ −4.5). The latter layer was formed between the late 1980’s and mid 1990’s during the last cold state of the Labrador Sea and underwent substantial modification since its formation through the admixture of Irminger Water, Iceland Slope Water and North East Atlantic Deep Water, which is reflected in its less radiogenic ɛHf signature. The overall behavior of Hf in the water column suggests its higher sensitivity to local changes in weathering inputs on annual to decadal timescales. Although application of Hf isotopes as a tracer for global water mass mixing is complicated by their susceptibility to incongruent weathering inputs they are a promising tracer of local processes in restricted basins such as the Labrador Sea.
    Type: Article , PeerReviewed
    Format: text
    DOI: 10.1016/j.gca.2016.11.024
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    OceanRep: Article in a Scientific Journal - peer-reviewed
  • 5
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    A review of nitrogen isotopic alteration in marine sediments (2012)
    AGU (American Geophysical Union)
    In:  Paleoceanography, 27 (4). PA4203.
    Details
    Publication Date: 2019-09-23
    Description: Key Points: Use of sedimentary nitrogen isotopes is examined; On average, sediment 15N/14N increases approx. 2 per mil during early burial; Isotopic alteration scales with water depth Abstract: Nitrogen isotopes are an important tool for evaluating past biogeochemical cycling from the paleoceanographic record. However, bulk sedimentary nitrogen isotope ratios, which can be determined routinely and at minimal cost, may be altered during burial and early sedimentary diagenesis, particularly outside of continental margin settings. The causes and detailed mechanisms of isotopic alteration are still under investigation. Case studies of the Mediterranean and South China Seas underscore the complexities of investigating isotopic alteration. In an effort to evaluate the evidence for alteration of the sedimentary N isotopic signal and try to quantify the net effect, we have compiled and compared data demonstrating alteration from the published literature. A 〉100 point comparison of sediment trap and surface sedimentary nitrogen isotope values demonstrates that, at sites located off of the continental margins, an increase in sediment 15N/14N occurs during early burial, likely at the seafloor. The extent of isotopic alteration appears to be a function of water depth. Depth-related differences in oxygen exposure time at the seafloor are likely the dominant control on the extent of N isotopic alteration. Moreover, the compiled data suggest that the degree of alteration is likely to be uniform through time at most sites so that bulk sedimentary isotope records likely provide a good means for evaluating relative changes in the global N cycle.
    Type: Article , PeerReviewed
    Format: text
    DOI: 10.1029/2012PA002321
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    OceanRep: Article in a Scientific Journal - peer-reviewed
  • 6
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    Extensive hydrogen supersaturations in the western South Atlantic Ocean suggest substantial underestimation of nitrogen fixation (2014)
    AGU (American Geophysical Union) | Wiley
    In:  Journal of Geophysical Research: Oceans, 119 (7). pp. 4340-4350.
    Details
    Publication Date: 2019-09-23
    Description: The nitrogen cycle is fundamental to Earth's biogeochemistry. Yet major uncertainties of quantification remain, particularly regarding the global oceanic nitrogen fixation rate. Hydrogen is produced during nitrogen fixation and will become supersaturated in surface waters if there is net release from diazotrophs. Ocean surveys of hydrogen supersaturation thus have the potential to illustrate the spatial and temporal distribution of nitrogen fixation, and to guide the far more onerous but quantitative methods for measuring it. Here we present the first transect of high resolution measurements of hydrogen supersaturations in surface waters along a meridional 10,000 km cruise track through the Atlantic. We compare measured saturations with published measurements of nitrogen fixation rates and also with model-derived values. If the primary source of excess hydrogen is nitrogen fixation and has a hydrogen release ratio similar to Trichodesmium, our hydrogen measurements would point to similar rates of fixation in the North and South Atlantic, roughly consistent with modelled fixation rates but not with measured rates, which are lower in the south. Possible explanations would include any substantial nitrogen fixation by newly discovered diazotrophs, particularly any having a hydrogen release ratio similar to or exceeding that of Trichodesmium; under-sampling of nitrogen fixation south of the equator related to excessive focus on Trichodesmium; and methodological shortcomings of nitrogen fixation techniques that cause a bias towards colonial diazotrophs relative to unicellular forms. Alternatively our data are affected by an unknown hydrogen source that is greater in the southern half of the cruise track than the northern.
    Type: Article , PeerReviewed
    Format: text
    Format: text
    DOI: 10.1002/2014JC010017
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    OceanRep: Article in a Scientific Journal - peer-reviewed
  • 7
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    Holocene water mass changes in the Labrador Current (2019)
    SAGE Publications
    In:  The Holocene, 29 (4). pp. 676-690.
    Details
    Publication Date: 2022-01-31
    Description: The Labrador Current is part of the anticlockwise subpolar gyre and plays a major role in the formation of North Atlantic Deep Water. It is influenced by the West Greenland and Baffin currents supplying warmer Atlantic and cold polar waters, respectively. During the early Holocene, at the final stage of the last deglaciation, meltwater and iceberg discharge caused highly variable conditions in the Labrador Current. In order to assess its sensitivity to such freshening, this study provides a well-resolved Holocene paleoclimatic record from the Labrador Shelf. Based on benthic foraminiferal faunal and alkenone biomarker analyses, we differentiated four distinct climatic periods in the western Labrador Sea. From 8.9 to 8.6 ka BP, the Labrador Shelf was dominated by polar water outflow from Baffin Bay and covered by perennial sea ice. Between 8.6 and 7.4 ka BP, a strong subsurface inflow of warmer Atlantic water masses is ascribed to an intensification and redirection of the West Greenland Current. At 7.4 ka BP, the decreased influence of Atlantic water masses on the Labrador Shelf marks the establishment of winter convection leading to the formation of Labrador Sea Water in the central basin. Concurrently, an intensified polar water outflow through the Canadian Gateways strengthened the inner Labrador Current, and higher primary productivity suggests longer spring blooms because of a shorter sea-ice season during the Holocene Thermal Maximum. In the late Holocene after 3 ka BP, periodic fluctuations of primary productivity may tentatively be correlated with stronger and weaker northwesterly winds.
    Type: Article , PeerReviewed
    Format: text
    Format: text
    DOI: 10.1177/0959683618824752
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    OceanRep: Article in a Scientific Journal - peer-reviewed
  • 8
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    Labrador Sea freshening at 8.5 ka BP caused by Hudson Bay Ice Saddle collapse (2019)
    Nature Research
    In:  Nature Communications, 10 (586).
    Details
    Publication Date: 2022-01-31
    Description: A significant reduction in the Atlantic Meridional Overturning Circulation and rapid northern Hemisphere cooling 8200 years ago have been linked to the final melting of the Laurentide Ice Sheet. Although many studies associated this cold event with the drainage of Lake Agassiz-Ojibway, recent model simulations have shown that the Hudson Bay Ice Saddle collapse would have had much larger effects on the Atlantic Meridional Overturning Circulation than the lake outburst itself. Based on a combination of Mg/Ca and oxygen isotope ratios of benthic foraminifera, this study presents the first direct evidence of a major Labrador shelfwater freshening at 8.5 ka BP, which we associate with the Hudson Bay Ice Saddle collapse. The freshening is preceded by a subsurface warming of the western Labrador Sea, which we link to the strengthening of the West Greenland Current that could concurrently have accelerated the ice saddle collapse in Hudson Bay.
    Type: Article , PeerReviewed
    Format: text
    Format: text
    DOI: 10.1038/s41467-019-08408-6
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    OceanRep: Article in a Scientific Journal - peer-reviewed
  • 9
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    Origin of the deep Bering Sea nitrate deficit : constraints from the nitrogen and oxygen isotopic composition of water column nitrate and benthic nitrate fluxes (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2005. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Global Biogeochemical Cycles 19 (2005): GB4005, doi:10.1029/2005GB002508.
    Description: On the basis of the normalization to phosphate, a significant amount of nitrate is missing from the deep Bering Sea (BS). Benthic denitrification has been suggested previously to be the dominant cause for the BS nitrate deficit. We measured water column nitrate 15N/14N and 18O/16O as integrative tracers of microbial denitrification, together with pore water-derived benthic nitrate fluxes in the deep BS basin, in order to gain new constraints on the mechanism of fixed nitrogen loss in the BS. The lack of any nitrate isotope enrichment into the deep part of the BS supports the benthic denitrification hypothesis. On the basis of the nitrate deficit in the water column with respect to the adjacent North Pacific and a radiocarbon-derived ventilation age of ∼50 years, we calculate an average deep BS (〉2000 m water depth) sedimentary denitrification rate of ∼230 μmol N m−2 d−1 (or 1.27 Tg N yr−1), more than 3 times higher than high-end estimates of the average global sedimentary denitrification rate for the same depth interval. Pore water-derived estimates of benthic denitrification were variable, and uncertainties in estimates were large. A very high denitrification rate measured from the base of the steep northern slope of the basin suggests that the elevated average sedimentary denitrification rate of the deep Bering calculated from the nitrate deficit is driven by organic matter supply to the base of the continental slope, owing to a combination of high primary productivity in the surface waters along the shelf break and efficient down-slope sediment focusing along the steep continental slopes that characterize the BS.
    Description: This study was supported by NSF grants OCE-0136449 and OCE-9981479 to D. M. S., OCE-0118126 and OCE-0324987 to D. C. M., and DFG grant LE 1326/1-1 to M. F. L. The BS cruise was funded by grant OPP-9912122.
    Keywords: Bering Sea ; Denitrification ; Nitrate isotopes
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: application/pdf
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  • 10
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    Glacial-interglacial modulation of the marine nitrogen cycle by high-latitude O2 supply to the global thermocline (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2004. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 19 (2004): PA4007, doi:10.1029/2003PA001000.
    Description: An analysis of sedimentary nitrogen isotope records compiled from widely distributed marine environments emphasizes the global synchrony of denitrification changes and provides evidence for a strong temporal coupling of these variations to changes in nitrogen fixation as previously inferred. We explain the global coherence of these records by a simple physical control on the flux of dissolved oxygen to suboxic zones and the coupling to fixation via the supply of phosphorus to diazotrophs in suitable environments. According to our hypothesis, lower glacial-stage sea surface temperature increased oxygen solubility, while stronger winds in high-latitude regions enhanced the rate of thermocline ventilation. The resultant colder, rapidly flushed thermocline lessened the spatial extent of denitrification and, consequently, N fixation. During warm periods, sluggish circulation of warmer, less oxygen rich thermocline waters caused expansion of denitrification zones and a concomitant increase in N fixation. Local fluctuations in export productivity would have modulated this global signal.
    Description: Financial support for this work was provided by the Natural Sciences and Engineering Research Council of Canada and by a WHOI postdoctoral fellowship to MK.
    Keywords: Isotopes ; Fixation ; Denitrification
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: application/pdf
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