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  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 86 (1987), S. 2036-2043 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We report the observation of NH(a 1Δ) formation in a one-photon process during the ArF laser (193 nm) photolysis of ammonia. We have used laser-induced fluorescence to detect NH(a) and ND(a) and report the rotational and vibrational populations generated. We have also reinvestigated the generation of NH(a) in the 248 nm photolysis of HN3 and find substantial vibrational excitation in contrast to the results of previous workers. We give estimates for the quantum yields for NH(a) and ND(a) in the photolysis of ammonia based on comparison with the yield in 248 nm photolysis of HN3.
    Type of Medium: Electronic Resource
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