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  • 1
    Electronic Resource
    Electronic Resource
    Ionics 3 (1997), S. 44-51 
    ISSN: 1862-0760
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The self-diffusion coefficient for a stochastically nonuniform thermodynamic system is represented as the mean value of the transition rates. A model for the ionic transport in solid oxide electrolytes is proposed. The existence of percolation cluster of the doping cations is taken into account in the model. The maximum of the concentration dependence of the ionic conductivity is explained by the blocking effect and random distribution of traps. The problem of inconsistency of theoretical and experimental values for the pre-exponential factor is discussed and an approach is proposed to overcome this disagreement.
    Type of Medium: Electronic Resource
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