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High resolution infrared spectroscopy of deuterium in p-H2 matrix (1991)

Chan, Man-Chor ; Xu, Li-Wei ; Gabrys, Charles M. ; [et al.]

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 95 (1991), S. 9404-9407

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ISSN: 1089-7690

Source: AIP Digital Archive

Topics: Physics , Chemistry and Pharmacology

Notes: The high resolution spectrum of the fundamental band of deuterium impurity embedded in solid parahydrogen has been studied using a difference frequency laser spectrometer. This observation represents the first case of high resolution matrix spectroscopy in solid hydrogen. Both the Q1←0(0) and Q1←0(1) transitions were resolved into sharp features with a typical linewidth of (approximately-less-than) 10 MHz, while both the S1←0(0) and S1←0(1) transitions appeared to be much broader with widths of ∼0.07 cm−1. A discussion of the linewidths based on homogeneous broadening is presented.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1063/1.461169

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