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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 451 (1979), S. 109-114 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: 121Sb Mössbauer Spectra of Antimony (V) Compounds. IIIThe Mössbauer resonance effect of 121Sb has been studied in the antimony(V) compounds I-VI. Isomer shift and quadrupole splitting variations are considered in the light of results of vibrational spectroscopy and in part of X-ray data. The antimony iodine azides II and IV, respectively, were obtained by reactions of R3Sb (R = CH3, C6H5) with iodine azide.
    Notes: Die bei 4,2 K erhaltene 121Sb-Mößbauer-Spektren von Me3Sb(N3)2 (I), Me3SbIN3 (II), Me3SbI2 (III), (C6H5)3SbIN3 (IV), KSbCl5N3 (V) und [Cl4SbNCO]3 (VI) werden mitgeteilt und die aus der Isomerieverschiebung und der Quadrupolaufspaltung ermittelten Informationen mit schwingungsspektroskopischen und zum Teil mit kristallographischen Daten in Beziehung gebracht. Die Antimoniodidazide II bzw. IV werden aus R3Sb (R = CH3, C6H5) und Iodazid erhalten.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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