ISSN:
1040-0397
Keywords:
Catalysis
;
reaction mechanism
;
channel electrode
;
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The shape of the current-voltage curves at a channel electrode have been calculated for the various situations of the catalytic (EC′) mechanism. In particular the halfwave potential and limiting current are found to be highly sensitive to the solution-flow rate and to the concentrations of the mediator and substrate employed. These observations provide a ready method of unambiguously characterizing the different pathways.
Additional Material:
22 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/elan.1140040207