Keywords:
Chemistry, Inorganic.
;
Electronic books.
Description / Table of Contents:
Advances in Inorganic Chemistry presents timely and informative summaries of the current progress in a variety of subject areas within inorganic chemistry ranging from bio-inorganic to solid state studies. Thisacclaimed serial features reviews written by experts in the area and is an indispensable reference to advanced researchers. Each volume of Advances in Inorganic Chemistry contains an index, and each chapter is fully referenced.
Type of Medium:
Online Resource
Pages:
1 online resource (417 pages)
Edition:
1st ed.
ISBN:
9780080578910
Series Statement:
Issn Series ; v.Volume 42
URL:
https://ebookcentral.proquest.com/lib/geomar/detail.action?docID=403304
DDC:
546
Language:
English
Note:
Front Cover -- Advances in Inorganic Chemistry, Volume 42 -- Copyright Page -- Contents -- Chapter 1. Substitution Reactions of Solvated Metal Ions -- I. Introduction -- II. Solvent Exchange and Ligand Substitution on Main Group Metal Ions -- III. Solvent Exchange and Ligand Substitution on Transition Metal Ions -- IV. Solvent Exchange and Ligand Substitution on the Trivalent Lanthanides and Diosouranium(VI) -- V. Solvent Exchange and Ligand Substitution on Some Molybdenum and Tungsten Cluster Complexes -- VI. Concluding Comments -- VII. Appendix: Ligand Abbreviations, Formulae, and Structures -- References -- Chapter 2. Lewis Acid-Base Behavior in Aqueous Solution: Some Implications for Metal Ions in Biology -- I. Introduction -- II. Lewis Acid-Base Interactions in the Gas Phase -- III. Comparison of Behavior of Lewis Acids and Bases in Aqueous Solution and in the Gas Phase -- IV. Significance of HSAB Ideas for Zinc-Containing Metalloenzymes -- V. Chelate Ring Size and Metal Ion Selectivity -- VI. The Neutral Oxygen Donor -- VII. The Negative Oxygen Donor -- VIII. The Nitrogen Donor -- IX. Sulfur Donors -- X. Systems Containing More Than One Metal Ion-The Reverse Chelate -- References -- Chapter 3. The Synthesis and Structure of Organosilanols -- I. General Introduction -- II. General Synthetic Methods -- III. The Acidity and Basicity of the Silanol Group -- IV. Structural Studies of Silanols -- V. Summary and Conclusions -- References -- Chapter 4. Studies of the Soluble Methane Monooxygenase Protein System: Structure, Component Interactions, and Hydroxylation Mechanism -- I. Introduction -- II. Structural Studies of sMMO Hydroxylase -- III. Component Interactions -- IV. Mechanism of Hydroxylation -- V. Conclusions -- References.
,
Chapter 5. Alkyl, Hydride, and Hydroxide Derivatives of the s- and p-Block Elements Supported by Poly(pyrazolyl)borato Ligation: Models for Carbonic Anhydrase, Receptors for Anions, and the Study of Controlled Crystallographic Disorder -- I. Introduction -- II. Syntheses, Structures, and Steric Properties of Poly(pyrazoly1)hydroborato Ligands -- III. Terminal Alkyl Derivatives of the s- and p-Block Metals Supported by Poly(pyrazoly1)borato Ligation -- IV. Terminal Hydride Derivatives of the s- and p-Block Metals Supported by Poly(pyrazoly1)borato Ligation -- V. Terminal Hydroxide Derivatives of the s- and p-Block Metals Supported by Poly(pyrazo1yl)borato Ligation -- VI. Anion Coordination by Protonated Tris(pyrazoly1)hydroborato Derivatives -- VII. Controlled Crystallographic Disorder' in [TpRR']MX Complexes: Bond Length Artifacts as Determined by Single Crystal X-Ray Diffraction -- VIII. Summary -- References -- Index -- Contents of Previous Volumes.
