Keywords:
Oxidation.
;
Electronic books.
Type of Medium:
Online Resource
Pages:
1 online resource (204 pages)
Edition:
1st ed.
ISBN:
9781483160801
URL:
https://ebookcentral.proquest.com/lib/geomar/detail.action?docID=1822002
Language:
English
Note:
Front Cover -- Periodate Oxidation of Diol and Other Functional Groups: Analytical and Structural Applications -- Copyright Page -- Table of Contents -- PREFACE -- INTRODUCTION -- CHAPTER 1. HISTORY -- Literature Cited -- CHAPTER 2. PREPARATION AND PROPERTIES OF PERIODATES -- Preparation -- Solubility -- Stability of Aqueous Solutions -- Standard Potentials -- Ionization of Periodic Acid -- Structure of Periodates -- Literature Cited -- CHAPTER 3. MECHANISM OF PERIOD ATE OXIDATION -- 1,2-Diols -- 1,2-Hydroxycarbonyl Compounds and 1,2-Diketones -- 1,2-Aminoalcohols -- Active Méthylène Groups -- Literature Cited -- CHAPTER 4. ANOMALOUS PERIODATE OXIDATIONS -- Overoxidation -- Sulfur-containing Compounds -- Phenols -- Flavanols -- Amines -- Amino Acids -- Unsaturated Sugars -- Amino Sugars -- Proteins -- Oxidations at Elevated Temperature -- Oxidations in the Presence of Light -- Literature Cited -- CHAPTER 5. PERIODATE OXIDATION IN STRUCTURAL STUDIES -- Structure Assignment based on Periodate Oxidation Information -- Structure Assignment based on Periodate Oxidation and Other Information -- Structure and End-group Assay of Polysaccharides -- Nature of the Product of Periodate Oxidation -- Literature Cited -- CHAPTER 6. ANALYTICAL METHODS -- Conditions of the Oxidation -- Determination of Oxidant Consumption -- Other Methods for Periodate Determination -- Determination of Acid Produced -- Determination of Other Acids -- Determination of Formaldehyde -- Determination of Acetaldehyde -- Determination of Ammonia and Amines -- Determination of Carbon Dioxide -- Recommended General Methods -- Conclusions -- Literature Cited -- CHAPTER 7. SYNTHETIC AND OTHER APPLICATIONS OF PERIODATE OXIDATIONS -- Literature Cited -- AUTHOR INDEX -- SUBJECT INDEX.
