Keywords:
Organometallic chemistry.
;
Electronic books.
Description / Table of Contents:
A series of critical reviews and perspectives focussing on specific aspects of organometallic chemistry interfacing with other fields of study are provided.
Type of Medium:
Online Resource
Pages:
1 online resource (165 pages)
Edition:
1st ed.
ISBN:
9781849732802
Series Statement:
Issn Series
URL:
https://ebookcentral.proquest.com/lib/geomar/detail.action?docID=1185904
DDC:
547.05
Language:
English
Note:
Organometallic Chemistry -- CONTENTS -- Preface -- Synergistic effects in the activation of small molecules by s-block elements -- 1 Introduction -- 2 Historical perspective of bimetallic s-block ates -- 3 Chemistry of alkyl lithium magnesiates -- 4 Chemistry of the turbo-Grignard reagent iPrMgCl·LiCl -- 5 Chemistry of the turbo-Hauser bases (TMP)MgCl·LiCl, (TMP)2Mg·2LiCl and (DA)MgCl·LiCl -- 6 Chemistry of other alkali metal magnesiate complexes -- 7 Conclusions -- References -- Air-stable chiral primary phosphines: part (i) synthesis, stability and applications -- 1 Introduction -- 2 Stability and synthesis -- 3 Applications -- 4 Conclusions -- References -- Open-shell organometallics: reactivity at the ligand -- 1 Introduction -- 2 Ligand redox non-innocence -- 3 Ligand centred radical-type reactivity in open-shell organometallic chemistry and catalysis -- 4 Summary and conclusions -- References -- Alkali/coinage metals - organolithium, organocuprate chemistry -- 1 The alkali metals -- 2 Group 11 -- Abbreviations -- References -- Group 2 (Be-Ba) and Group 12 (Zn-Hg) -- 1 Scope and organisation of the review -- 2 Group 2 -- 3 Group 12 -- References -- Organo-transition metal cluster complexes -- 1 Introduction -- 2 Reviews -- 3 Theory -- 4 High-nuclearity clusters -- 5 Group 8 -- 6 Group 9 -- 7 Group 10 -- 8 Group 11 -- 9 Mixed-metal clusters -- Abbreviations -- References -- Highlights in low-coordinate group 14 organometallic chemistry -- 1 Activation of small molecules with heavy alkynes -- 2 Heavy alkyne chemistry -- 3 The chemistry of compounds with element-element double bonds -- 4 Heavy group 14 elements as ligands to transition metals -- References.
