Note: Nuclear Magnetic Resonance -- Contents -- Chapter 1 Nuclear Shielding -- 1 Introduction -- 2 Chemical Shift Scales -- 3 Basic Aspects of Nuclear Shielding -- A Magnetic Field-dependent Chemical Shifts -- B Developments in Theory -- 4 Calculations of Nuclear Shielding -- A Ab Initio Calculations -- B Semi-empirical Calculations -- 5 Transmissions of Shielding Effects within Molecules -- A Introduction -- B Inductive and Resonance Effects -- C Magnetic Anisotropy Effects -- D The Ring Current Effects -- E Electric Field Effects -- F Intramolecular Dispersion Forces -- G Steric Effects -- H Intramolecular Hydrogen-bonding -- I Isotope Shifts -- J Shielding Anisotropies -- 6 Shieldings of Particular Nuclear Species -- A Introduction -- B Proton Chemical Shifts -- C Carbon Chemical Shifts -- D Fluorine Chemical Shifts -- E Nitrogen Chemical Shifts -- F Chemical Shifts of Nuclei Other Than H, C, F, and N -- Chapter 2 Nuclear Spin-Spin Coupling -- 1 Introduction -- 2 Basic Theory -- A Ramsey's Equations -- B The Average Energy Approximation -- C Useful General Expressions -- D The Finite Perturbation Theory (FPT) -- E Coupling by π-Electrons -- F The Variation Method -- G SI Units -- 3 Recent Theoretical Work -- A Calculations on H2 or HD -- B Ab Initio Calculations of Coupling in Small Molecules -- C Semi-empirical Calculations -- D Theoretical Work on π-Electron Coupling -- E The Anisotropy of Electron-coupled Nuclear Spin Interactions -- F Solvent Effects on Coupling -- 4 Coupling of Directly Bonded Nuclei -- A Coupling between 13C and 1H -- B Coupling between 15N and 1H -- C Coupling between 31P and 1H -- D Coupling between 1H and Other Nuclei -- E 1J(13C13C)and 1J(13C14/15N) -- F Coupling between 13C and 31P -- G Coupling between 13C and 19F -- H 1J(13CM) where M is a Metal -- I Couplings to 19F, except 1J(19F31P) -- J Couplings between 31P and 19F. , K Other One-bond Couplings involving 31P -- 5 Coupling between Atoms Separated by Two Chemical Bonds, 2J -- A Geminal Proton-Proton Coupling across Carbon -- B Geminal Proton-Proton Coupling across Other Elements -- C 2J(13CCH) -- D Coupling of Other Elements to Hydrogen through Carbon -- E 2J(19FP19F) and 2J(19FPH) -- F 2J(19FM19F), where M is a Metal -- G 2J(19FC19F) -- H 2J(13CO31P) and 2J(13CC31P) -- I 2J(31PO31P) and 2J(31PS31P) -- J 2J(31PM31P), where M is a Metal -- K Other Two-bond Couplings -- 6 Coupling between Atoms Separated by Three Chemical Bonds, 3J -- A Coupling of Hydrogen Atoms through Two Carbon Atoms -- B 3J(HNCH) and 3J(HOCH) -- C 3J(13CCCH) -- D Coupling to Fluorine through Two Carbon Atoms. 3J(HCC19F), 3J(13CCC19F), and 3J(19FCC19F) -- E Three-bond Couplings involving 31P and 1H -- F Miscellaneous Three-bond Couplings -- 7 Coupling between Nuclei Separated by Four or More Chemical Bonds -- A Long-range Coupling between Protons -- Long-range H-H Coupling in Saturated Systems -- Long-range H-H Coupling in Unsaturated Systems -- B Long-range Couplings involving at least One Nucleus other than H -- Saturated Systems-Coupling between 1H and 19F -- Saturated Systems-Coupling between Other Nuclei -- Unsaturated Systems -- C 'Through-space' Coupling -- 8 Experimental Work of Significance for the Measurement or Interpretation of SpinSpin Coupling Constants -- A Multiple-resonance Experiments -- B Bandshape Analyses -- C Effects of Paramagnetic Materials -- D Other Experimental Techniques -- Chapter 3 Nuclear Spin Relaxation -- 1 Introduction -- 2 Nuclear Spin Relaxation in Gases -- A Introduction -- B Theoretical Developments -- C Diatomic Gases -- D Polyatomic Gases -- Pure Gases -- Stepped T1/ρ vs. ρ Plot -- CH4-O2 and CH4-NO Mixtures -- E Self-diffusion Measurements -- 3 Spin Relaxation in Liquids -- A Pure Liquids. , Molecular Rotation -- Studies of Anisotropic Rotation -- Relaxation by internal rotation of functional groups -- Relaxation in water -- Determination of nuclear quadrupole coupling constants -- Studies of Scalar Relaxation -- Relaxation in glasses and viscous liquids -- B Molecular Motion and Association in Mixtures of Liquids -- C Electrolyte Solutions -- Diamagnetic Solutions -- Paramagnetic Solutions -- D Studies of Critical Phenomena in Liquids -- E 13C Relaxation Studies -- F Methods for Selective Measurement of T1 and T2 -- 4 Spin-echo Experiments in Liquids -- A Self-diffusion Measurements -- B Spin-echo Studies of Fluid Flow -- C Carr-Purcell Spin-echo Experiments -- 5 Nuclear Spin Relaxation and Diffusion in Liquid Crystals -- A Thermotropic Liquid Crystals -- B Lyotropic Liquid Crystals -- 6 Spin Relaxation in Solids -- A N.M.R. Saturation in Solids -- B Nuclear Dipolar Relaxation -- C Relaxation by Rotational Motion -- D Spin-Lattice Relaxation by Spin-Rotational and Anisotropic Chemical Shielding Interactions -- E Spin-Lattice Relaxation due to Paramagnetic Impurities -- F Spin-Lattice Relaxation by Nuclear Quadrupole Interaction -- G Spin-Lattice Relaxation Time Measurements in Miscellaneous Solids -- Molecular Solids -- Ionic Solids -- Antiferromagnetic Solids -- Metallic Hydrides -- Hexagonal Ice -- Molecules Bound to Surfaces -- H Self-diffusion in Molecular Crystals -- I Ferroelectric Phase Transitions -- 7 Pulsed N.M.R. in Solids -- A Application of Multiple-pulse Experiments to Line-narrowing in Solids -- B Application of Multiple-pulse Experiments to the Study of Molecular Motion -- C Pulsed Double Nuclear Magnetic Resonance Experiments -- Chapter 4 Experimental Techniques -- 1 Introduction -- 2 The Magnet -- A Permanent Magnets -- B Electromagnets -- C Superconducting Magnets -- D Control of Homogeneity -- E Stability. , 3 Sensitivity -- 4 Frequency Generation -- A Single Resonance -- B Double Resonance -- Homonuclear -- Heteronuclear -- Noise -- Universal Shift Reference -- 5 The Probe -- A Single-coil Systems -- B Crossed-coil Systems -- C Double Resonance -- D Field-Frequency Lock -- E General Construction -- F Field Modulation -- G Variable-temperature Operation -- H Rapid Sample Spinning -- 6 The Preamplifier -- 7 The Receiver -- 8 Modulation Schemes -- 9 Computer Techniques -- 10 Pulsed Spectrometers -- 11 Measurement of Relaxation Times -- A Values of T1 -- C.W. Methods -- Pulse Methods -- B Values of T2 -- C.W. Methods -- Pulse Methods -- 12 Miscellaneous Topics -- A Stochastic Resonance -- B Fourier Difference Spectroscopy -- Chapter 5 Spectral Analysis -- 1 New Spin Systems Studied -- Analysis of N.M.R. Spectra of the Type [AMX]2 with J(XX') = 0 -- 2 New Methods of Tackling Known Spin Systems -- A Superoperator Direct Method Least-squares Analysis of N.M.R. Spectra -- B A Systematic Approach to the [AB]2, [AB]2MX, and Derived Systems -- C Use of Double Quantum Transitions -- Double Resonance: Perturbation of Double Quantum Transitions -- Effect of Double Irradiation (Tickling) of Single Quantum Transitions or Double Quantum Transitions in Systems Simplified by Double Resonance -- 3 Studies of Known Spin Systems -- A Systems involving Protons Only -- Aliphatic Systems -- Olefinic Systems -- Heterocyclic Systems -- Aromatic Systems -- B Compounds containing Fluorine -- 2,2'-, 3,3'-, and 4,4'-Dihalogenobiphenyl Compounds ABCD, ABCDX -- Pyridine Compounds -- Pentafluorophenol, (AM)2X -- Benzene, Naphthalene, Phenanthrene, and Biphenyl Compounds -- Tetrafluorodichlorocyclopropanes, [AX]2, A4 -- 1,1,2,2-Tetrafluoroethane [AMX]2 -- C Compounds containing Phosphorus -- Bis(dialkylphosphines) -- The [AMX18]2 System -- Tri-(3-furyl)phosphine, ABCX. , 1-Phospha-2,6-dioxacyclohexanes -- 1-Phospha-2,5-dioxa(diaza, dithia)cyclopentanes -- Bis-(5,5-dimethyl-1-phospha-2-oxo-6-thionocyclo-hexane) -- D Organometallic Compounds -- Triphenyl Group IV Element Lithium Compounds, [AB]2C -- Allenic Derivatives of Tin, Lead, and Mercury AB2X -- Cycloheptatrienyl Manganese Tricarbonyl Compounds, A[BCXY]2, ABCDEXYZ -- Aryl Derivatives of Mercury, [AB]2C, [AB]2X, [AB]2 -- 4 General Comments -- Books and Reviews -- Computer Programs -- Chapter 6 Bandshape Phenomena for Fluids -- 1 General Introduction -- A Current Developments -- B Coverage of the Report -- C Nomenclature, Notation, and Units -- D Reviews and Symposia -- 2 Experimental Features -- Miscellaneous -- 3 Exchange of Magnetic Sites -- A Theoretical Work -- B Examples of Intramolecular Exchange -- Hindered Internal Rotation -- Nitrogen Inversion -- Ring Inversion -- Phosphorus-containing Compounds -- Metal Complexes -- C Examples of Intermolecular Exchange -- Studies of Ligand Exchange (The Swift-Connick Approach) -- Other Studies of Intermolecular Exchange -- 4 Effects of Quadrupolar Nuclei -- A Theoretical Work -- B Resonance of Spin-½ nuclei Coupled to Quadrupolar Nuclei -- C N.M.R. Spectra of Quadrupolar Nuclei -- Nitrogen -- Other Nuclei -- D Effects of Magnetic Site Exchange on N.M.R. Spectra for Spin Systems containing Quadrupolar Nuclei -- 5 Relaxation Effects - Linewidths -- A Theoretical Work -- B Paramagnetic Effects -- C Gas-phase Studies -- D Miscellaneous Width Studies -- 6 Relaxation Effects-Saturation -- 7 Bandshapes in Multiple Resonance -- Cases including Exchange -- Chapter 7 Multiple Resonance -- 1 Introduction -- 2 Theory of Multiple Resonance -- 3 Double Resonance in the Presence of Chemical Exchange -- 4 Chemical Applications of Multiple-resonance Techniques -- Spin Decoupling -- Generalized Overhauser Effect -- INDOR. , Nuclear Overhauser Effect (NOE).