Keywords:
Polymerization.
;
Electronic books.
Description / Table of Contents:
The first book to provide a broad overview of all the major facets of coordination polymer research in one place.
Type of Medium:
Online Resource
Pages:
1 online resource (439 pages)
Edition:
1st ed.
ISBN:
9781847558862
URL:
https://ebookcentral.proquest.com/lib/geomar/detail.action?docID=1185396
DDC:
547.7
Language:
English
Note:
Coordination Polymers -- Contents -- Chapter 1 Introduction -- 1.1 Introduction -- 1.2 Crystal Engineering, Supramolecular Chemistry, Metallosupramolecules -- 1.3 What is a Coordination Polymer? -- 1.4 Synthetic Techniques -- 1.5 Design, Analysis, Application -- References -- Chapter 2 Nets: A Tool for Description and Design -- 2.1 Introduction -- 2.2 Defining Networks -- 2.3 Identifying and Naming Nets -- 2.4 1D Nets -- 2.5 2D Nets -- 2.6 Common 3D Nets -- 2.6.1 3-Connected Nets -- 2.6.2 4-Connected Nets -- 2.6.3 5-Connected Nets -- 2.6.4 6-Connected Nets -- 2.6.5 Higher Connected Nets -- 2.6.6 Mixed Connectivity Nets -- 2.7 Rod Packings -- References -- Chapter 3 Interpenetration -- 3.1 Introduction -- 3.2 Nomenclature -- 3.3 1D Interpenetration -- 3.4 2D Interpenetration -- 3.5 3D Interpenetration -- 3.6 Interpenetration of Nets of Different Composition, Topology and Dimensions -- 3.7 Self-penetration -- 3.8 Other Entangled Systems -- References -- Chapter 4 Malleability of Coordination Polymers -- 4.1 Introduction -- 4.2 Supramolecular Isomerism -- 4.3 Malleability of Building Blocks -- 4.4 Synthetic Approach -- 4.5 Solvent Effects -- 4.6 Other Guests -- 4.7 Counterions -- 4.8 Weaker Interactions -- 4.9 Conclusion -- References -- Chapter 5 Transition Metal Coordination Polymers -- 5.1 Introduction -- 5.2 Pseudohalide Ligands -- 5.2.1 The Cyanide Ligand -- 5.2.2 The Azide Ligand -- 5.2.3 NCX Ligands (X=O, S, Se) -- 5.2.4 Small Polynitrile Ligands (e.g. dca/tcm) -- 5.3 Larger Nitrile Donor Ligands -- 5.3.1 Neutral Ligands -- 5.3.2 Anionic Nitrile Ligands -- 5.4 Pyridyl Donor Ligands -- 5.4.1 2-Connecting Ligands -- 5.4.2 3-Connecting Ligands -- 5.4.3 4-Connecting Ligands -- 5.5 Five-membered Ring Nitrogen Donor Ligands -- 5.5.1 2-Connecting Ligands -- 5.5.2 3-Connecting Ligands -- 5.5.3 Other Connectors -- 5.6 N-Oxide Ligands.
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5.7 Carboxylate Ligands -- 5.7.1 2-Connecting Ligands -- 5.7.2 3-Connecting Ligands -- 5.7.3 4-Connecting Ligands -- 5.8 Other Ligands -- 5.9 Mixed Donor Atom Ligands -- 5.10 Mixed Ligand Coordination Polymers -- References -- Chapter 6 Rare Earth Coordination Polymers -- 6.1 Introduction -- 6.2 Cyanide/Nitrile and Pseudohalide Ligands -- 6.3 Five-membered Ring Donors -- 6.4 Pyridyl Donor Ligands -- 6.5 N-Oxide Donors -- 6.6 Rare Earth-Carboxylate Polymers -- 6.6.1 Monocarboxylate Ligands -- 6.6.2 Dicarboxylate Ligands -- 6.6.3 Tricarboxylate Ligands -- 6.6.4 Tetracarboxylate Ligands -- 6.7 Other Ligands -- 6.7.1 Oxalate Coordination Polymers -- 6.7.2 Chloranilic Acid and Dihydroxybenzoquinone -- 6.7.3 Polymers with Sulfonate-containing Ligands -- 6.7.4 Amide Ligands -- 6.7.5 Pyridylcarboxylate Ligands -- 6.8 Mixed 3d/4f Coordination Polymers -- 6.8.1 Cyanide-based Bimetallic Polymers -- 6.8.2 Carboxylate-based Bimetallic Polymers -- 6.8.3 Pyridylcarboxylate Ligands -- 6.8.4 Other Mixed O/N Donor Ligands -- 6.9 Actinide Coordination Polymers -- References -- Chapter 7 Organometallic Networks -- 7.1 Introduction -- 7.2 Large Aromatic Ligands -- 7.2.1 Cation-p Interactions in Ag(I)-PAH Systems -- 7.2.2 Cation-p Interactions with Cyclophanes -- 7.2.3 Non-aromatic Cation-p Interactions -- 7.3 Organometallic Complexes as Ligands -- 7.3.1 Metallocene Bridging Ligands -- 7.3.2 Metal-Quinone Bridging Complexes -- 7.4 Isocarbonyl Polymers -- 7.5 R3Sn/R3Pb Systems -- 7.5.1 Metal-Cyanide Polymers -- 7.5.2 (Triorganostannyl)tetrazole Polymers -- References -- Chapter 8 Inorganic-Organic Hybrids -- 8.1 Introduction -- 8.2 0D Metal-Oxide Substructures -- 8.3 1D Metal-Oxide Substructures -- 8.3.1 2D Polymers with 1D Metal-Oxide Substructures -- 8.3.2 3D Polymers with 1D Metal-Oxide Substructures -- 8.4 2D Metal-Oxide Substructures (Pillared Layers) -- References.
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Chapter 9 Magnetism in Coordination Polymers -- 9.1 Introduction -- 9.2 Long-range Magnetic Ordering -- 9.2.1 Introduction -- 9.2.2 Molecule-based Magnets -- 9.2.3 Single-chain Magnets -- 9.3 Spin Crossover -- 9.3.1 Introduction -- 9.3.2 Five-membered Heterocyclic Ring Bridging Ligands -- 9.3.3 Six-membered Ring Bridging Ligands -- 9.3.4 Cyanide Bridges in Hofmann Phases -- References -- Chapter 10 Porous Coordination Polymers -- 10.1 Introduction -- 10.1.1 Terminology -- 10.2 Designing Permanent Porosity -- 10.2.1 Flexible Porosity -- 10.2.2 Rigid Porosity -- 10.3 Solvent Exchange -- 10.3.1 Flexible Guest Exchange -- 10.3.2 Rigid Guest Exchange -- 10.4 Gas Storage -- 10.4.1 Hydrogen Gas Storage -- 10.4.2 Methane Gas Storage -- 10.4.3 Carbon Dioxide Gas Storage -- 10.4.4 Other Gases -- 10.5 Ion Exchange -- 10.6 Multifunctional Porous Materials -- 10.7 Conclusion -- References -- Chapter 11 Acentric and Chiral Networks -- 11.1 Introduction -- 11.2 Acentric Networks for Non-linear Optical Behaviour -- 11.3 Chiral Networks -- 11.3.1 1D Helices from Achiral Components -- 11.3.2 2D Chiral Nets from Achiral Components -- 11.3.3 3D Chiral Nets from Achiral Components -- 11.3.4 Chiral Ligands -- 11.3.5 Applications -- References -- Chapter 12 Reactive Coordination Polymers -- 12.1 Introduction -- 12.2 Topotactic Reactions -- 12.3 Chemically Reactive Ligands -- 12.4 Catalysis -- References -- Chapter 13 Other Properties of Coordination Polymers -- 13.1 Introduction -- 13.2 Luminescence -- 13.3 Redox Activity -- 13.4 Conductivity -- 13.5 Negative Thermal Expansion -- 13.6 Multifunctional Materials -- References -- Subject Index.
