In:
Zeitschrift für Naturforschung B, Walter de Gruyter GmbH, Vol. 72, No. 9 ( 2017-9-26), p. 631-638
Abstract:
The equiatomic rare earth iridium indides RE IrIn ( RE =La, Pr, Nd, Er–Yb) were synthesized by reaction of the elements in induction or muffle furnaces and were characterized through X-ray powder patterns. The structures of LaIr 0.86 In 1.14 , PrIr 0.89 In 1.11 , NdIr 0.94 In 1.06 , ErIrIn (all ZrNiAl type, P 6̅2 m ), and YbIrIn (TiNiSi type, Pnma ) were refined from single crystal X-ray diffractometer data. Refinements of the occupancy parameters revealed small degrees of solid solutions with indium substitution on the iridium sites. Chemical bonding analyses and electronic structure calculations indicate the dominance of metallic bonding in addition to partial ionic interactions between the cations and polyanions, as well as covalent contributions between the indium and iridium atoms.
Type of Medium:
Online Resource
ISSN:
1865-7117
,
0932-0776
DOI:
10.1515/znb-2017-0086
Language:
English
Publisher:
Walter de Gruyter GmbH
Publication Date:
2017
detail.hit.zdb_id:
2078109-X
detail.hit.zdb_id:
124635-5