In:
Pure and Applied Chemistry, Walter de Gruyter GmbH, Vol. 91, No. 7 ( 2019-07-26), p. 1149-1158
Abstract:
The possibility to apply solventless conditions for the Baylis-Hillman reaction of 5-hydroxymethyl furfural (HMF) and its glucosylated analog, glucosyloxymethyl furfural (GMF) has been investigated. This study shows that highly functionalized adducts can be obtained in fair to good yields, under the conditions combining the renewability of the substrates, the straightforwardness of the strategy, and the lowered cost and toxicity of the solvent conditions. The issue of the polarity of the furanic substrate is addressed by comparing HMF with furfural and GMF.
Type of Medium:
Online Resource
ISSN:
1365-3075
,
0033-4545
DOI:
10.1515/pac-2019-0215
Language:
English
Publisher:
Walter de Gruyter GmbH
Publication Date:
2019
detail.hit.zdb_id:
2022101-0