In:
Main Group Metal Chemistry, Walter de Gruyter GmbH, Vol. 45, No. 1 ( 2022-09-24), p. 208-212
Abstract:
A new Cd( ii ) coordination polymers, formulated as [Cd(1,4-chdc)(L)] n ( 1 ) (L = 1-(1 H -imidazo[4,5- f ][1,10] phenanthrolin-2-yl)naphthalen-2-ol ligands and 1,4-H 2 chdc = 1,4-cyclohexanedicarboxylate acid), were successfully synthesized by using L ligand and 1,4-H 2 chdc acid under hydrothermal conditions and characterized by single crystal X-ray elemental analyses, diffraction, and IR spectroscopy. Each Cd( ii ) atom is a distorted pentagonal bipyramidal geometry connecting the deprotonated 1,4-chdc anion to form a 2D layer, and a 2D layer is formed into a 3D supramolecular structure by the π–π stacking interactions between neighboring layers.
Type of Medium:
Online Resource
ISSN:
2191-0219
DOI:
10.1515/mgmc-2022-0020
Language:
English
Publisher:
Walter de Gruyter GmbH
Publication Date:
2022
detail.hit.zdb_id:
2602433-0