In:
Acta Crystallographica Section E Crystallographic Communications, International Union of Crystallography (IUCr), Vol. 76, No. 5 ( 2020-05-01), p. 736-741
Abstract:
The title compound, bis(1,2-diphenyl-2-sulfanylideneethanethiolato-κ 2 S , S ′)(1,3,5-triaza-7-phosphaadamantane-κ P )cobalt(II) dichloromethane hemisolvate, [Co(pdt) 2 (PTA)]·0.5C 2 H 4 Cl 2 or [Co(C 14 H 10 S 2 ) 2 (C 6 H 12 N 3 P)]·0.5C 2 H 4 Cl 2 , contains two phenyldithiolene (pdt) ligands and a 1,3,5-triaza-7-phosphaadamantane (PTA) ligand bound to cobalt with the solvent 1,2-dichloroethane molecule located on an inversion center. The cobalt core exhibits an approximately square-pyramidal geometry with partially reduced thienyl radical monoanionic ligands. The supramolecular network is consolidated by hydrogen-bonding interactions primarily with nitrogen, sulfur and chlorine atoms, as well as parallel displaced π-stacking of the aryl rings. The UV–vis, IR, and CV data are also consistent with monoanionic dithiolene ligands and an overall Co II oxidation state.
Type of Medium:
Online Resource
ISSN:
2056-9890
DOI:
10.1107/S2056989020005447
DOI:
10.1107/S2056989020005447/zl2776sup1.cif
DOI:
10.1107/S2056989020005447/zl2776Isup2.hkl
Language:
Unknown
Publisher:
International Union of Crystallography (IUCr)
Publication Date:
2020
detail.hit.zdb_id:
2843762-7