In:
Acta Crystallographica Section B Structural Science, International Union of Crystallography (IUCr), Vol. 64, No. 5 ( 2008-10-01), p. 521-526
Abstract:
The structure of Ga 2 O 3 (ZnO) 6 was determined using single-crystal X-ray diffraction techniques in the space group Cmcm . The metal ion sublattice resembles some of the Zn ions in the wurtzite ZnO structure. The oxygen ion sublattice in Ga 2 O 3 (ZnO) 6 also resembles some of the O ions in ZnO. Structural relationships between Ga 2 O 3 (ZnO) 6 and ZnO are discussed, illustrating the process for obtaining the centrosymmetric Ga 2 O 3 (ZnO) 6 structure from the noncentrosymmetric ZnO. Structures of phases in the homologous series Ga 2 O 3 (ZnO) m are predicted on the basis of the structural data for Ga 2 O 3 (ZnO) 6 . The structures of even m are constructed by simply extending the structure units seen in Ga 2 O 3 (ZnO) 6 , while those of odd m consist of structure units which are of different types from those used for even m .
Type of Medium:
Online Resource
ISSN:
0108-7681
DOI:
10.1107/S0108768108021125
DOI:
10.1107/S0108768108021125/kd5022sup1.cif
DOI:
10.1107/S0108768108021125/kd5022Isup2.hkl
DOI:
10.1107/S0108768108021125/kd5022sup3.pdf
Language:
Unknown
Publisher:
International Union of Crystallography (IUCr)
Publication Date:
2008
detail.hit.zdb_id:
2020841-8
SSG:
13