In:
Applied Physics Letters, AIP Publishing, Vol. 109, No. 15 ( 2016-10-10)
Abstract:
We report photoluminescence (PL) imaging and spectroscopy of air-suspended carbon nanotubes (CNTs) before and after exposure to a brief (20 s) UV/ozone treatment. These spectra show enhanced PL intensities in 10 out of 11 nanotubes that were measured, by as much as 5-fold. This enhancement in the luminescence efficiency is caused by oxygen defects which trap excitons. We also observe an average 3-fold increase in the D-band Raman intensity further indicating the creation of defects. Previous demonstrations of oxygen doping have been carried out on surfactant-coated carbon nanotubes dissolved in solution, thus requiring substantial longer ozone/UV exposure times (∼15 h). Here, the ozone treatment is more efficient because of the surface exposure of the air-suspended CNTs. In addition to enhanced PL intensities, we observe narrowing of the emission linewidth by 3–10 nm. This ability to control and engineer defects in CNTs is important for realizing several optoelectronic applications such as light-emitting diodes and single photon sources.
Type of Medium:
Online Resource
ISSN:
0003-6951
,
1077-3118
Language:
English
Publisher:
AIP Publishing
Publication Date:
2016
detail.hit.zdb_id:
211245-0
detail.hit.zdb_id:
1469436-0
