In:
Journal of Applied Physics, AIP Publishing, Vol. 94, No. 6 ( 2003-09-15), p. 3823-3827
Abstract:
Alternative Er doping into anatase (A–) or rutile (R−)TiO2 can be achieved by O2 pressure control during Er-doped TiO2 deposition using laser ablation. An x-ray absorption fine structure analysis of the atomic coordination around Er revealed the dynamics of Er–O clustering in A– and R−TiO2. The Er local structure in A−TiO2 can be determined by a Ti–O arrangement of the host crystal surrounding Er, while that in R−TiO2 can be decided by the Er–O chemical properties rather than the Ti–O arrangement. Moreover, a substitution of Er for Ti induced O deficit in A−TiO2 and induced Ti removal in R−TiO2. These differences can be explained by the ErO6 stabilization mechanism based on the spontaneous symmetry reduction (SSR) theory. The Ti–O arrangement in A−TiO2 prevents the SSR, resulting in ErO6 instability. However, ErO6 is stabilized in the host crystal because the SSR is smoothly induced in R−TiO2.
Type of Medium:
Online Resource
ISSN:
0021-8979
,
1089-7550
Language:
English
Publisher:
AIP Publishing
Publication Date:
2003
detail.hit.zdb_id:
220641-9
detail.hit.zdb_id:
3112-4
detail.hit.zdb_id:
1476463-5
