In:
Synthesis, Georg Thieme Verlag KG, Vol. 55, No. 16 ( 2023-08), p. 2586-2594
Abstract:
A Cu-catalyzed C(sp2)–P bond forming reaction using an acylphosphine as the phosphorus source is reported; with CuCl2 as the catalyst, 34 examples of aryl iodides and bromides were converted into triarylphosphines in good to excellent yield. A preliminary study of the mechanism was carried out and found that a radical intermediate is not involved. This reaction is an extension of the application of acylphosphines in Cu-catalyzed reactions and shows their potential as a phosphination reagent in the synthesis of tertiary phosphines.
Type of Medium:
Online Resource
ISSN:
0039-7881
,
1437-210X
Language:
English
Publisher:
Georg Thieme Verlag KG
Publication Date:
2023
detail.hit.zdb_id:
204080-3
detail.hit.zdb_id:
2033062-5