In:
The European Physical Journal Applied Physics, EDP Sciences, Vol. 98 ( 2023), p. 15-
Abstract:
Formic acid (FA) dehydrogenation at ambient conditions is a promising route for hydrogen (H 2 ) generation but still suffers from low activity and selectivity. Here, potassium hydroxide (KOH) and 3-aminopropyl triethoxysilane (APTES) modified porous carbon derived from the pyrolysis of rice straw (RSNPC) offers an effective support to promote the formation of ultrafine PdAu nanoparticles (NPs). Benefiting from the small sizes of PdAu NPs, the Pd 0.7 Au 0.3 /RSNPC catalyst exhibits excellent catalytic performance for FA dehydrogenation reaction with a high turnover frequency (TOF) of 6794.3 mol H 2 mol catalyst −1 h −1 at ambient conditions, outperforming most of reported catalysts for FA dehydrogenation under similar conditions.
Type of Medium:
Online Resource
ISSN:
1286-0042
,
1286-0050
DOI:
10.1051/epjap/2023220271
Language:
English
Publisher:
EDP Sciences
Publication Date:
2023
detail.hit.zdb_id:
1468654-5
SSG:
11