In:
Dalton Transactions, Royal Society of Chemistry (RSC), Vol. 52, No. 6 ( 2023), p. 1806-1819
Abstract:
The iron( iii ) anionic complex based on a pyruvic acid thiosemicarbazone ligand with the lithium cation Li[Fe III (thpy) 2 ]·3H 2 O (1) has been synthesized and characterized by FTIR spectroscopy, powder and single crystal X-ray diffraction, direct current magnetic susceptibility measurements, and 57 Fe Mössbauer spectroscopy. Moreover, the molecular structure of the [Fe(thpy) 2 ] − anion has been determined for the first time. The [Fe(thpy) 2 ] − units in the triclinic P 1̄ lattice of 1 are assembled into layers parallel to the bc plane. The Li + cations and water molecules are located between the layers and the structure is stabilized by hydrogen bonding. The [Fe(thpy) 2 ] − anions form interconnected dimer pairs through hydrogen bonds and short contacts with Fe⋯Fe separation of 6.7861(4) Å. According to dc magnetic measurements, compound 1 demonstrates an incipient spin-crossover transition from the LS ( S = 1/2) to the HS ( S = 5/2) state above 250 K. The Bleaney–Bowers equation for a model of an isolated LS dimer with a mean-field correction was applied to fit the experimental data of magnetic susceptibility dependence on temperature in the temperature range of 2–250 K. The intra-dimer J 1 = −1.79(1) K and inter-dimer J 2 = −0.24(3) K antiferromagnetic coupling constants were defined. The analysis of the 57 Fe Mössbauer spectra at 80 K and 296 K confirms the presence of the shortened distances between the iron nuclei. Moreover, the influence of the lithium cation on the stabilization of the LS state was shown for the [Fe(thpy) 2 ] − anion. BS-DFT calculations for the optimized structure of two isolated [Fe(thpy) 2 ] − anions also correctly predict a weak exchange J 1 (calc) = −0.92 K. DFT calculations revealed the OPBE (GGA-type) functional that correctly predicts the spin-crossover transition for the iron( iii ) thpy compounds. Besides, the effect of the N 2 O 4 , N 2 S 2 O 2 , and N 2 Se 2 O 2 coordination environments on the energy stabilization of the LS state of iron( iii ) anionic thpy complexes was noted as well.
Type of Medium:
Online Resource
ISSN:
1477-9226
,
1477-9234
Language:
English
Publisher:
Royal Society of Chemistry (RSC)
Publication Date:
2023
detail.hit.zdb_id:
2001339-5
detail.hit.zdb_id:
1472887-4
