In:
Chemical Communications, Royal Society of Chemistry (RSC), Vol. 58, No. 43 ( 2022), p. 6296-6299
Abstract:
The brevijanazines are novel p -nitrobenzoylated piperazines isolated from Aspergillus brevijanus . Their structures were elucidated by spectroscopic analysis, X-ray crystallography and total synthesis. Heterologous biosynthesis, precursor feeding and in vitro microsomal assays unveiled the biosynthetic pathway to the brevijanazines, featuring a cytochrome P450 oxygenase that converts p -aminobenzoic acid to p -nitrobenzoic acid.
Type of Medium:
Online Resource
ISSN:
1359-7345
,
1364-548X
Language:
English
Publisher:
Royal Society of Chemistry (RSC)
Publication Date:
2022
detail.hit.zdb_id:
215830-9
detail.hit.zdb_id:
1472881-3