In:
Chemical Communications, Royal Society of Chemistry (RSC), Vol. 58, No. 6 ( 2022), p. 859-862
Abstract:
The catalytic activity in amine-borane dehydrogenation is shown for the first time for Ln( ii ) species using complexes [{( p-t Bu-C 6 H 4 ) 2 CH} 2 M·L] (M = Yb, Sm, L = (DME) 2 , TMEDA). The protonation of M( ii )–C bonds with HNR 1 R 2 BH 3 affords amidoborane complexes [M(NR 1 R 2 BH 3 ) 2 L], which under excess HNMe 2 BH 3 transform to [NMe 2 BH 2 NMe 2 BH 3 ] − derivatives, both serving as the dehydrocoupling intermediates.
Type of Medium:
Online Resource
ISSN:
1359-7345
,
1364-548X
Language:
English
Publisher:
Royal Society of Chemistry (RSC)
Publication Date:
2022
detail.hit.zdb_id:
1472881-3