In:
European Journal of Organic Chemistry, Wiley, Vol. 2017, No. 18 ( 2017-05-10), p. 2641-2647
Abstract:
Trifluoromethanesulfonic acid catalyzed C–O bond cleavage leading to the preparation of functional esters in the presence of N ‐methylpyrrolidin‐2‐one (NMP) was accomplished. Various substrates were well tolerated, and a gram‐scale experiment was successfully realized. DFT calculations indicated that NMP plays a decisive role in accelerating nucleophilic attack of the functional acid to generate the functional esters in chlorobenzene.
Type of Medium:
Online Resource
ISSN:
1434-193X
,
1099-0690
DOI:
10.1002/ejoc.v2017.18
DOI:
10.1002/ejoc.201700514
Language:
English
Publisher:
Wiley
Publication Date:
2017
detail.hit.zdb_id:
1475010-7