In:
European Journal of Inorganic Chemistry, Wiley, Vol. 2017, No. 25 ( 2017-07-07), p. 3144-3149
Abstract:
In the search for multifunctional molecular materials, we designed an enantiopure pair of Fe II complexes with chiral, chelating ( R )/( S )‐4,5‐pinenepyridyl‐2‐pyrazine ligands exhibiting three inherent physical properties: chirality, spin crossover, and dielectric switching. The geometrical change resulted in coupling of the spin‐crossover transition at 187 K to dielectric switching. Both compounds were found to display light‐induced spin crossover that was thermally unstable above ca. 40 K. The coupling of two hysteretic properties, electric and magnetic, renders these compounds as potential switching devices.
Type of Medium:
Online Resource
ISSN:
1434-1948
,
1099-0682
DOI:
10.1002/ejic.v2017.25
DOI:
10.1002/ejic.201700609
Language:
English
Publisher:
Wiley
Publication Date:
2017
detail.hit.zdb_id:
1475009-0
detail.hit.zdb_id:
1409951-2