In:
European Journal of Inorganic Chemistry, Wiley, Vol. 2005, No. 7 ( 2005-04), p. 1383-1387
Abstract:
Cleavage of the all‐iron( III ) μ 2 ‐O 2– ‐linked dimer [Fe III 3 O(L) 2 ‐(OAc) 4 ] 2 O ( 3 ) with lithium chloride yields [Fe III 3 O(L) 2 (OAc) 4 ]Cl ( 4 ) and with sodium benzoate, in combination with complete acetate‐to‐benzoate coligand exchange, gives [Fe III 3 O(L) 2 ‐(OBz) 4 ]OBz ( 5 ). Reduction of the all‐Fe III complex 5 [Fe/L/OBz = 3:2:(4+1)] with sodium iodide affords the homonuclear mixed‐valent cluster [Fe II Fe III 2 O(L) 3 (OBz) 3 ] ( 6 ) (Fe/L/OBz = 1:1:1) and requires fundamental coligand‐to‐ligand exchange. Likewise, when the all‐Fe III dimer [Fe III 3 O(L) 2 (OAc) 4 ] 2 O ( 3 ) (Fe/L/OAc = 3:2:4) is cleaved with nickel acetate, the mixed‐valent heteronuclear complex [Ni II Fe III 2 O(L) 3 (OAc) 3 ] ( 7 ) (M/L/OAc = 1:1:1) is formed. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)
Type of Medium:
Online Resource
ISSN:
1434-1948
,
1099-0682
DOI:
10.1002/ejic.v2005:7
DOI:
10.1002/ejic.200400821
Language:
English
Publisher:
Wiley
Publication Date:
2005
detail.hit.zdb_id:
1475009-0