In:
Chemistry – A European Journal, Wiley, Vol. 26, No. 6 ( 2020-01-27), p. 1269-1273
Abstract:
The active six‐membered cyclo‐FLP 6 undergoes a rapid P/B addition reaction to carbon dioxide. At elevated temperature, the resulting heterobicyclo[2.2.2]octane derived product 7 undergoes ring opening and equilibrates with the cyclotetramer (7) 4 . In the large macrocyclic structure, four monomeric six‐membered cyclo‐FLP units are connected by four CO 2 molecules to form the supramolecular ring system. The P/B cyclo‐FLP 6 undergoes a variety of additional cycloaddition reactions.
Type of Medium:
Online Resource
ISSN:
0947-6539
,
1521-3765
DOI:
10.1002/chem.201905171
Language:
English
Publisher:
Wiley
Publication Date:
2020
detail.hit.zdb_id:
1478547-X