In:
Chemistry – An Asian Journal, Wiley, Vol. 18, No. 22 ( 2023-11-16)
Abstract:
By using a simple co‐precipitation method, new Fe 2 O 3 ‐based nanocatalysts (samples) were synthesized. The samples were composites of two or three transition metal oxides, MO x (M=Fe, Mn, Co, Ni, and Cu). The average size of CuO crystallites in the composites composed of two oxide components (CuO−Fe 2 O 3 ) was about 14.3 nm, while in those composed of three (CuO−MnO x −Fe 2 O 3 ), the composite's phase compositions were almost in the amorphous form when annealing the sample at 300 °C. The latter sample had a specific surface area higher than that of the former, 207.9 and 142.1 g/m 2 , respectively, explaining its higher catalytic CO oxidation. The CO conversion over the CuO−MnO x −Fe 2 O 3 ‐300 catalyst (1 g of catalyst, 2600 ppm of CO concentration in air, and 1.0 L/min of gas flow rate) begins at about 40 °C; the temperature for 50 % CO conversion ( t 50 ) is near 82 °C; and CO removal is almost complete at t 99 ≈110 °C. The activity of the optimal sample was tested in different catalytic conditions, thereby observing a high durability of 99–100 % CO conversion at 130 °C. The obtained results were derived from XRD, FTIR, BET, SEM, elemental analysis and mapping, as well as catalytic experiments.
Type of Medium:
Online Resource
ISSN:
1861-4728
,
1861-471X
DOI:
10.1002/asia.202300683
Language:
English
Publisher:
Wiley
Publication Date:
2023
detail.hit.zdb_id:
2233152-9
detail.hit.zdb_id:
2233006-9
