In:
Journal of Applied Polymer Science, Wiley, Vol. 131, No. 23 ( 2014-12-05)
Abstract:
Free radical miniemulsion polymerization of styrene (St), St/acrylonitrile 3 : 1 mixture or methylmethacrylate in the presence of multiwalled carbon nanotubes (MWCNT) was proven as a convenient way to obtain homogenous hybrids with perspectives in associated applications like foams specialties materials. Miniemulsion polymerization was viable up to 2% wt. MWCNT to monomer, without agglomerations. The grafting on MWCNT during the polymerization occurs without the need for supplementary functionalization and the polymer grafted nanotubes showed stable dispersions in the polymer solvent. Monomer polarity affected the grafting ability during the polymerization process. The nanocomposites obtained after purification and drying were used in foaming process. MWCNT presence in the related nanocomposites decreased the pore sizes in foam‐like materials (for all three different matrices). At 1 wt % MWCNT content, low density ( 〈 0.3 g/cm 3 ), low pore size ( 〈 10 μm) and high cell density ( 〉 10 9 cell/cm 3 ) were achieved. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131 , 41148.
Type of Medium:
Online Resource
ISSN:
0021-8995
,
1097-4628
Language:
English
Publisher:
Wiley
Publication Date:
2014
detail.hit.zdb_id:
1491105-X