In:
Angewandte Chemie International Edition, Wiley, Vol. 56, No. 22 ( 2017-05-22), p. 6022-6066
Kurzfassung:
This Review traces the discovery of the Wittig–Still rearrangement and its applications in organic synthesis. Its relationship to Wittig rearrangements is discussed along with detailed analysis of E/Z‐ and diastereoselectivity. Modifications of the products arising from the Wittig–Still rearrangement are reviewed in the context of increased complexity in intermediates potentially useful in target‐oriented synthesis. Early applications of the Wittig–Still rearrangement to modifications of steroids are reviewed as are applications to various terpene and alkaloid natural product targets and miscellaneous compounds. To the best of our knowledge, the literature is covered through December 2016.
Materialart:
Online-Ressource
ISSN:
1433-7851
,
1521-3773
DOI:
10.1002/anie.201611329
Sprache:
Englisch
Verlag:
Wiley
Publikationsdatum:
2017
ZDB Id:
2011836-3
ZDB Id:
123227-7
