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    Online Resource
    Online Resource
    Ligand‐Promoted meta ‐C−H Functionalization of Benzylamines
    Wiley ; 2017
    In:  Angewandte Chemie Vol. 129, No. 18 ( 2017-04-24), p. 5207-5211
    Details
    In: Angewandte Chemie, Wiley, Vol. 129, No. 18 ( 2017-04-24), p. 5207-5211
    Abstract: Meta‐C−H functionalization of benzylamines has been developed using a Pd II /transient mediator strategy. Using 2‐pyridone ligands and 2‐carbomethoxynorbornene (NBE‐CO 2 Me) as the mediator, arylation, amination, and chlorination of benzylamines are realized. This protocol features a broad substrate scope and is compatible with heterocylic coupling partners. Moreover, the loading of the Pd can be lowered to 2.5 mol % by using the optimal ligand.
    Type of Medium: Online Resource
    ISSN: 0044-8249 , 1521-3757
    URL: Issue
    URL: Article
    DOI: 10.1002/ange.v129.18
    DOI: 10.1002/ange.201701803
    RVK:
    VA 2100
    RVK:
    VN 5020
    Language: English
    Publisher: Wiley
    Publication Date: 2017
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