In:
Angewandte Chemie, Wiley, Vol. 126, No. 9 ( 2014-02-24), p. 2475-2478
Abstract:
β‐Lactam scaffolds are considered to be ideal building blocks for the synthesis of nitrogen‐containing compounds. A new palladium‐catalyzed oxidative carbonylation of N ‐allylamines for the synthesis of α‐methylene‐β‐lactams is reported. DFT calculations suggest that the formation of β‐lactams via a four‐membered‐ring transition state is favorable.
Type of Medium:
Online Resource
ISSN:
0044-8249
,
1521-3757
DOI:
10.1002/ange.201309081
Language:
German
Publisher:
Wiley
Publication Date:
2014
detail.hit.zdb_id:
506609-8
detail.hit.zdb_id:
1479266-7