Description: Public fear for environmental and health impacts or potential leakage of CO2 from geological reservoirs is among the reasons why over the past decade CCS has not yet been deployed on a large enough scale so as to meaningfully contribute to mitigate climate change. Storage of CO2 under the seabed moves this climate mitigation option away from inhabited areas and could thereby take away some of the opposition towards this technology. Given that in the event of CO2 leakage for sub-seabed CCS the ocean would function as buffer for receiving this greenhouse gas, rather than the atmosphere, offshore CCS could particularly address concerns over the climatic impacts of CO2 seepage. In this paper we point out that recent geological studies confirm that leakage for individual offshore CCS operations may be highly unlikely from a technical point of view, if storage sites are well chosen, well managed and well monitored. But we argue that on a global long-term scale, for an ensemble of thousands or millions of storage sites, leakage of CO2 could take place in certain cases and/or countries for e.g. economic, institutional, legal or safety cultural reasons. We investigated what the impact could be in terms of temperature increase and ocean acidification if leakage would nevertheless occur, and addressed the question what the relative roles could be of on- and offshore CCS if mankind desires to divert the atmospheric damages resulting from climate change. For this purpose, we constructed a top-down energy-environment-economy model, with which we performed a probabilistic cost-benefit analysis of climate change mitigation with on- and offshore CCS as specific CO2 abatement options. One of our main conclusions is that even if there is non-zero leakage for CCS activity on a global scale, there is high probability that both onshore and offshore CCS could – on economic grounds – still account for anywhere between 20% and 80% of all future CO2 abatement efforts under a broad range of CCS cost assumptions.

Description: Cruise SO210 with RV SONNE to the active continental margin off Chile was conducted by shiptime exchange with RV METEOR. Funds for mobilizing the research team were provided by the German Science Foundation (DFG) in conjunction with the Collaborative Research Centre (SFB) 574 of the University of Kiel. In the first years, the SFB 574 investigated the pathways and fluxes of volatiles through the erosive subduction zone off Central America. For comparison, the studies were extended to the accretionary margin off Central Chile. Cruise SO210 is the last cruise conducted in the framework of SFB 574 and based on investigations of previous SFB-cruises on the RVs VIDAL GORMAZ and JAMES COOK. The first leg of cruise SO210 was dedicated to long gravity coring for volcanic ash layers from the erruptive Southern Volcanic Zone (SVZ) of the Andes that were either deposited as fallouts onto the incoming Nazca Plate or transported down the slope and across the Chile Trench. Eight gravity cores of 12 m length were retrieved seaward of the Chile Channel on the outer rise of the Nazca Plate. The second goal for coring was the description and dating of previously mapped submarine landslides as well as retrieval of slide-related material for geo-technical experiments. As the deployment frame for long coring had to be removed on the second leg we continued coring for mass-wasting and geochemistry with short cores. Ten gravity cores of 3 or 6 m barrel length were retrieved upslope of slides, the glide plane and redeposited material downslope of the slide evacuation area. This sampling activity was supported by detailed acoustic surveys with Parasound and multibeam to remap critical areas for mass wasting in search for events, e.g. triggered by the recent Mw 8.8 Maule Earthquake, such as flanks of submarine canyons or previously detected submarine slides and to fill data gaps in the existing bathymetric data. The major activity of the entire cruise was dedicated to the search and detailed sampling of manifestations of fluid discharge activity on the Chilean forearc. A total of 11 deployments with the video sled OFOS and 12 dives by the ROV KIEL 6000 were conducted for ground-truthing of information which indicated possible seep activity and has been obtained during previous cruises to the Chilean forearc. In five working areas we found manifestations of fluid discharge. In these areas the survey was followed by an intense sampling of bottom water, sediments, carbonates, mega and meiofauna and the deployment of instrumentation on the seafloor. The goal of these deployments was to measure in situ seabed methane emission rates and associated fluxes of sulfide and major electron acceptors such as oxygen at seep sites along the Chilean margin and to understand its controls. This was accompanied by CTD casts to trace oxygen and the fate of methane discharge in the water column. Sediment cores obtained by multicorer or ROV were used for the geochemical characterization of the pore water and microbiological studies which include turnover rate measurements, molecular studies, flow through experiments and sampling of active sediments. Authigenic carbonates obtained by TV-Grab or ROV were sampled for fauna, biomarker studies and investigations to reconstruct the growth structures, calcification processes and fluid-pathway systematic. The sampling of sediments and carbonates recovered a unique fauna with 79 different taxa, several of them appear to be species new to science.

Description: Carbon capture and storage (CCS), both on- and offshore, is expected to be an important technique to mitigate anthropogenic effects on global climate by isolating man-made carbon dioxide (CO2) in deep geological formations. In marine environments, however, the potential impacts of CO2 leakage, appropriate detection methods, and risk and pathways of atmospheric emissions are poorly defined. The natural CO2 gas seeps that occur in the relatively shallow waters off the coast of Panarea Island (Aeolian Islands, Italy) can be studied as a large-scale, real-world analogue of what might occur at a leaking offshore CCS site and what tools can be used to study it. The oceanographic survey PaCO2 was performed aboard R/V Urania from 27 July – 01 August 2011 (Naples – Naples). The project’s ship-time was funded by Eurofleets, with work being performed as a sub-project of the Seventh Framework Programme projects “ECO2” and “RISCS”, which provided subsidiary funding. Large amounts of data and samples were collected during the cruise which will be interpreted in the coming months, with preliminary results detailed here. Of particular importance was the discovery of much larger areas showing gas seepage than previously reported. Interdisciplinary measurements were performed at the Panarea seepage site. The international team of scientists onboard R/V Urania performed complementary sampling and measurements for biological, chemical, and physical parameters throughout the area. Together with the dedication of R/V Urania’s Captain and crew, and the eagerness and cooperation of the scientific crew, we were able to obtain excellent scientific results during this six-day cruise.