Description: The expedition ARK XIX/3 with the German icebreaking RV "Polarstern" was jointly organized between the Alfred Wegener Institute for Polar and Marine Research (AWI) and the Institut Français de Recherche pour l'Exploitation de la mer (IFREMER), the latter providing the unmanned deep-sea submersible "Victor 6000". AWI and IFREMER offered this unique combination of infrastructure in 2003 to European scientists to permit access on advanced technology in marine research to a broader community. Therefore, this cruise was not only a milestone in the Franco-German cooperation but also an important contribution to the European marine research initiatives. All still pictures and videos taken with "Victor 6000" during the expedition "VICTOR IN THE NORTH" are joint property of AWI and IFREMER with copyright by IFREMER. This material can be used for scientific purposes with the indication of IFREMER's copyright. It would be very much appreciated if the joint effort of AWI and IFREMER in organising the cruise ARK XIX/3 would be mentioned in the acknowledgements of any future publication written on the basis of material collected during the expedition. Any commercial or other than scientific use of either pictures or videos collected with "Victor 6000" needs the written formal approval of IFREMER. The entire cruise report is also available in digital format on a CD-ROM attached to this booklet because many of the pictures and graphs are in colour. All hand written dive log files are permanently stored at the AWI. For a certain period of time the cruise diary will be still accessible via the internet at www.polarstern-victor.de.

Description: Late Miocene to Quaternary volcanic rocks from the frontal arc to the back-arc region of the Central Volcanic Zone in the Andes show a wide range of delta 11B values (+4 to -7 ‰) and boron concentrations (6 to 60 ppm). Positive delta 11B values of samples from the volcanic front indicate involvement of a 11B-enriched slab component, most likely derived from altered oceanic crust, despite the thick Andean continental lithosphere, and rule out a pure crust-mantle origin for these lavas. The delta 11B values and B concentrations in the lavas decrease systematically with increasing depth of the Wadati-Benioff Zone. This across-arc variation in delta 11B values and decreasing B/Nb ratios from the arc to the back-arc samples are attributed to the combined effects of B-isotope fractionation during progressive dehydration in the slab and a steady decrease in slab-fluid flux towards the back arc, coupled with a relatively constant degree of crustal contamination as indicated by similar Sr, Nd and Pb isotope ratios in all samples. Modelling of fluid-mineral B-isotope fractionation as a function of temperature fits the across-arc variation in delta 11B and we conclude that the B-isotope composition of arc volcanics is dominated by changing delta 11B composition of B-rich slab-fluids during progressive dehydration. Crustal contamination becomes more important towards the back-arc due to the decrease in slab-derived fluid flux. Because of this isotope fractionation effect, high delta 11B signatures in volcanic arcs need not necessarily reflect differences in the initial composition of the subducting slab. Three-component mixing calculations for slab-derived fluid, the mantle wedge and the continental crust based on B, Sr and Nd isotope data indicate that the slab-fluid component dominates the B composition of the fertile mantle and that the primary arc magmas were contaminated by an average addition of 15 to 30 % crustal material.