Description:    Pesticides are widely used in modern agriculture to minimize financial losses and maintain food supplies. In southeast Asia, where agriculture is the principal economic activity, pesticides are considered essential, particularly in tropical regions seeking to enter the global economy by providing off-season fresh fruits and vegetables. The absence of a strong legal framework for pesticides facilitated a significant increase in the use of low-quality pesticides. Farmers ignore the risks, safety instructions, and protective directives when using pesticides. They are only concerned about the effectiveness of the pesticides for killing pests, without paying attention to the effects on their health and the environment. The improper usage of pesticides and the incorrect disposal of pesticide wastes contributed to the pollution of groundwater, surface water, and soil, and induced health problems in local communities. This paper describes the impact of the exposure of pesticides on human health and water resources in connection with the usage of pesticides and their management. Because of availability, the data are mainly taken for Northern Vietnam, and applied to the water quality in the delta; nevertheless, the problem relates to all countries in the delta, and similar situations may be found in other regions, particularly in Asia. Content Type Journal Article Category ORIGINAL ARTICLE Pages 1-9 DOI 10.1007/s10163-012-0081-x Authors Pham Thi Thuy, Laboratory of Applied Physical Chemistry and Environmental Technology, Department of Chemical Engineering, K.U. Leuven, W. de Croylaan 46, 3001 Leuven, Belgium Steven Van Geluwe, Laboratory of Applied Physical Chemistry and Environmental Technology, Department of Chemical Engineering, K.U. Leuven, W. de Croylaan 46, 3001 Leuven, Belgium Viet-Anh Nguyen, Institute of Environmental Science and Engineering, Hanoi University of Civil Engineering, 55 Giai Phong Road, Hanoi, Vietnam Bart Van der Bruggen, Laboratory of Applied Physical Chemistry and Environmental Technology, Department of Chemical Engineering, K.U. Leuven, W. de Croylaan 46, 3001 Leuven, Belgium Journal Journal of Material Cycles and Waste Management Online ISSN 1611-8227 Print ISSN 1438-4957

Description: Purpose   Global climate change (GCC), especially global warming, has affected the material cycling (e.g., carbon, nutrients, and organic chemicals) and the energy flows of terrestrial ecosystems. Persistent organic pollutants (POPs) were regarded as anthropogenic organic carbon (OC) source, and be coupled with the natural carbon (C) and nutrient biogeochemical cycling in ecosystems. The objective of this work was to review the current literature and explore potential coupling processes and mechanisms between POPs and biogeochemical cycles of C and nutrients in terrestrial ecosystems induced by global warming. Results and discussion   Global warming has caused many physical, chemical, and biological changes in terrestrial ecosystems. POPs environmental fate in these ecosystems is controlled mainly by temperature and biogeochemical processes. Global warming may accelerate the re-emissions and redistribution of POPs among environmental compartments via soil–air exchange. Soil–air exchange is a key process controlling the fate and transportation of POPs and terrestrial ecosystem C at regional and global scales. Soil respiration is one of the largest terrestrial C flux induced by microbe and plant metabolism, which can affect POPs biotransformation in terrestrial ecosystems. Carbon flow through food web structure also may have important consequences for the biomagnification of POPs in the ecosystems and further lead to biodiversity loss induced by climate change and POPs pollution stress. Moreover, the integrated techniques and biological adaptation strategy help to fully explore the coupling mechanisms, functioning and trends of POPs and C and nutrient biogeochemical cycling processes in terrestrial ecosystems. Conclusions and perspectives   There is increasing evidence that the environmental fate of POPs has been linked with biogeochemical cycles of C and nutrients in terrestrial ecosystems under GCC. However, the relationships between POPs and the biogeochemical cycles of C and nutrients are still not well understood. Further study is needed to explore the coupling mechanisms of POP environmental fate and C biogeochemical cycle by using the integrated techniques under GCC scenario and develop biological and ecological management strategies to mitigate GCC and environmental stressors. Content Type Journal Article Category SOILS, SEC 3 • REMEDIATION AND MANAGEMENT OF CONTAMINATED OR DEGRADED LANDS • REVIEW ARTICLE Pages 1-9 DOI 10.1007/s11368-011-0462-0 Authors Ying Teng, Key Laboratory of Soil Environment and Pollution Remediation, Institute of Soil Science, Chinese Academy of Sciences, Nanjing, 210008 People’s Republic of China Zhihong Xu, Environmental Futures Centre and School of Biomolecular and Physical Sciences, Griffith University, Nathan, QLD 4111, Australia Yongming Luo, Key Laboratory of Soil Environment and Pollution Remediation, Institute of Soil Science, Chinese Academy of Sciences, Nanjing, 210008 People’s Republic of China Frédérique Reverchon, Environmental Futures Centre and School of Biomolecular and Physical Sciences, Griffith University, Nathan, QLD 4111, Australia Journal Journal of Soils and Sediments Online ISSN 1614-7480 Print ISSN 1439-0108

Description:    Reduce, reuse, and recycle (3R) policies form the basis of waste management and global warming countermeasures globally, so we conducted a comparative study of 3R and waste management policies in the European Union (EU), USA, Korea, Japan, China, and Vietnam. An international workshop for 3R and waste management policymakers was held in Kyoto, Japan, and a bibliographic survey was also conducted to collect data. 3R policies are clearly given priority in the hierarchy of waste management in every country studied. Thermal recovery, which includes power generation from waste heat and methane gas collected from organic waste, is also a priority; this is consistent with the increased use of countermeasures to reduce greenhouse gas (GHG) emissions. In the EU, waste management is characterized by practical and effective 3R policies through the development of realistic regulations and by the policymakers’ desire to simplify management systems. The policy ideal in China, however, is the development of a circular economy that targets reductions in the amount and hazardousness of waste. Limits on the number of final disposal sites, strategies for procuring resources, and GHG emission countermeasures are closely linked with 3R policies, and further development of 3R policies in parallel with such issues is expected. Content Type Journal Article Pages 1-17 DOI 10.1007/s10163-011-0009-x Authors Shin-ichi Sakai, Environment Preservation Research Center, Kyoto University, Kyoto, 606-8501 Japan Hideto Yoshida, Japan Environmental Safety Corporation, Tokyo, Japan Yasuhiro Hirai, Environment Preservation Research Center, Kyoto University, Kyoto, 606-8501 Japan Misuzu Asari, Environment Preservation Research Center, Kyoto University, Kyoto, 606-8501 Japan Hidetaka Takigami, Research Center for Material Cycles and Waste Management, National Institute for Environmental Studies, Tsukuba, Japan Shin Takahashi, Center for Marine Environmental Studies, Ehime University, Matsuyama, Japan Keijirou Tomoda, Towa Technology, Hiroshima, Japan Maria Victoria Peeler, Hazardous Waste and Toxics Reduction, Washington State Department of Ecology, Olympia, WA, USA Jakub Wejchert, Sector in Unit G.4, Sustainable Production and Consumption, DG Environment, European Commission, Brussels, Belgium Thomas Schmid-Unterseh, Division of Product Responsibility, Avoidance, Recovery and Utilization of Product Waste, Federal Ministry for the Environment, Berlin, Germany Aldo Ravazzi Douvan, Italian Environmental Authority for EU Structural Funds, Ministry for the Environment Land and Sea, Rome, Italy Roy Hathaway, Waste Management Division, Department of Environment, Food and Rural Affairs, London, UK Lars D. Hylander, Department of Earth Sciences, Air and Water Science, Uppsala University, Uppsala, Sweden Christian Fischer, European Topic Centre on Sustainable Consumption and Production, Copenhagen, Denmark Gil Jong Oh, Resource Recirculation Center, National Institute of Environmental Research, Incheon, Korea Li Jinhui, Department of Environmental Science and Engineering, Tsinghua University, Beijing, China Ngo Kim Chi, Union for Scientific Research and Production on Chemical Engineering, Vietnam Academy of Science and Technology (VAST), Hanoi, Vietnam Journal Journal of Material Cycles and Waste Management Online ISSN 1611-8227 Print ISSN 1438-4957

Description: Purpose   Managing declining nutrient use efficiency in crop production has been a global priority to maintain high agricultural productivity with finite non-renewable nutrient resources, in particular phosphorus (P). Rapid spectroscopic methods increase measurement density of soil nutrients and improve the accuracy of rates of additional P inputs. Materials and methods   Soil P was measured by a multi-element energy-dispersive X-ray fluorescence spectroscopic (XRFS) method to estimate the spatial distribution of soil total (XRFS-P) and bioavailable P in a Fluvisol occurring on a 20-ha contiguous area comprised of seven elongated field strips under a wheat–maize rotation near the Quzhou Agricultural Experiment Station in the North China Plain. Results and discussion   Soil XRFS-P was highly variable along the length of the field strips and across the entire area after decades of continuous cultivation. A linear relationship existed between XRFS-P and bicarbonate-extractable P or Mehlich 3-extractable P, allowing a description of the spatial distribution of bioavailable P based on XRFS, in both directions of a two-dimensional grid covering the entire area ( p  〈 0.05). Distinct management zones were identified for more precise placement of additional P. Conclusions   Direct element-specific analysis and a high sample throughput make XRFS an indispensable component of a new approach to sustainably manage P, and other macronutrients of low atomic number Z such as K, Ca, or Cl in production fields, based on their site-specific variations in the soil. Concerning P, this rapid precision approach provides a promising avenue to manage soil P as a regionalized variable while preventing zones of deficiency or surplus P that can affect plant productivity or potential loss from a field, respectively. Content Type Journal Article Pages 1-12 DOI 10.1007/s11368-011-0347-2 Authors Thanh H. Dao, USDA-ARS Environmental Management and ByProducts Utilization Laboratory, BARC-East Bldg. 306, Beltsville, MD 20705, USA Yuxin X. Miao, College of Resources and Environmental Science, China Agricultural University, Beijing, People’s Republic of China Fusuo S. Zhang, College of Resources and Environmental Science, China Agricultural University, Beijing, People’s Republic of China Journal Journal of Soils and Sediments Online ISSN 1614-7480 Print ISSN 1439-0108

Description:    The conversion of biomass waste into resources as a recycling process is receiving increased interest due to the perceived need for a sustainable global carbon cycle and environmental considerations. Several treatment processes are being developed. Hydrothermal treatment is one of the most effective approaches, because water at high temperatures and high pressures behaves as a reaction medium with remarkable properties. In this work, the reaction behavior of guaiacol as a biomass model compound was studied in subcritical water at 483–563 K and in supercritical water at 653–673 K using a batch reactor. Guaiacol can be considered representative of the aromatic ring structures present in lignin, a major component of woody biomass. The chemical species formed in aqueous products were identified by gas chromatography/mass spectrometry and quantified using high-performance liquid chromatography. The effect of pressure and reaction time on the conversion process of guaiacol is discussed. The results obtained indicate that this method has potential for efficient organic waste conversion. Content Type Journal Article Pages 68-79 DOI 10.1007/s10163-010-0309-6 Authors Wahyudiono, Graduate School of Science and Technology, Kumamoto University, 2-39-1 Kurokami, Kumamoto, 860-8555 Japan Mitsuru Sasaki, Graduate School of Science and Technology, Kumamoto University, 2-39-1 Kurokami, Kumamoto, 860-8555 Japan Motonobu Goto, Bioelectrics Research Center, Kumamoto University, Kumamoto, Japan Journal Journal of Material Cycles and Waste Management Online ISSN 1611-8227 Print ISSN 1438-4957 Journal Volume Volume 13 Journal Issue Volume 13, Number 1

Description:    This study uses a bibliometric approach in identifying global research trends related to the anaerobic digestion of biomass for methane production using related literature in the Science Citation Index Expanded database, retrieved from the ISI Web of Science. The data used covers the period 1994–2011. The articles acquired from such literature were concentrated on the general analysis by scientific output, the research performances by countries, institutes, and collaborations, and the research trends by the frequency of author keywords, words in title, words in abstract, and ‘KeyWords plus’. The research outputs of anaerobic digestion for methane had notably increased in the field of environmental sciences, biotechnology and applied microbiology, environmental engineering, energy and fuels, and microbiology, while increased slightly in water resources. The USA with most publications and China with the highest growth rate were compared. Finally, author keywords, words in title and ‘KeyWords plus’ were analyzed contrastively, with the recent hotspots provided. Content Type Journal Article Category REVIEW Pages 1-8 DOI 10.1007/s10163-012-0094-5 Authors Li-Hong Wang, Department of Environmental Engineering, University of Science and Technology Beijing, Beijing, 100083 People’s Republic of China Qunhui Wang, Department of Environmental Engineering, University of Science and Technology Beijing, Beijing, 100083 People’s Republic of China Xiao Zhang, Department of Environmental Engineering, University of Science and Technology Beijing, Beijing, 100083 People’s Republic of China Weiwei Cai, Department of Environmental Engineering, University of Science and Technology Beijing, Beijing, 100083 People’s Republic of China Xiaohong Sun, Beijing Agro-Biotechnology Research Center, Beijing Academy of Agriculture and Forestry Sciences, Beijing, 100089 People’s Republic of China Journal Journal of Material Cycles and Waste Management Online ISSN 1611-8227 Print ISSN 1438-4957

Description: Purpose   The sensitivity of soil organic carbon to global change drivers, according to the depth profile, is receiving increasing attention because of its importance in the global carbon cycle and its potential feedback to climate change. A better knowledge of the vertical distribution of SOC and its controlling factors—the aim of this study—will help scientists predict the consequences of global change. Materials and methods   The study area was the Murcia Province (S.E. Spain) under semiarid Mediterranean conditions. The database used consists of 312 soil profiles collected in a systematic grid, each 12 km 2 covering a total area of 11,004 km 2 . Statistical analysis to study the relationships between SOC concentration and control factors in different soil use scenarios was conducted at fixed depths of 0–20, 20–40, 40–60, and 60–100 cm. Results and discussion   SOC concentration in the top 40 cm ranged between 6.1 and 31.5 g kg −1 , with significant differences according to land use, soil type and lithology, while below this depth, no differences were observed (SOC concentration 2.1–6.8 g kg −1 ). The ANOVA showed that land use was the most important factor controlling SOC concentration in the 0–40 cm depth. Significant differences were found in the relative importance of environmental and textural factors according to land use and soil depth. In forestland, mean annual precipitation and texture were the main predictors of SOC, while in cropland and shrubland, the main predictors were mean annual temperature and lithology. Total SOC stored in the top 1 m in the region was about 79 Tg with a low mean density of 7.18 kg Cm −3 . The vertical distribution of SOC was shallower in forestland and deeper in cropland. A reduction in rainfall would lead to SOC decrease in forestland and shrubland, and an increase of mean annual temperature would adversely affect SOC in croplands and shrubland. With increasing depth, the relative importance of climatic factors decreases and texture becomes more important in controlling SOC in all land uses. Conclusions   Due to climate change, impacts will be much greater in surface SOC, the strategies for C sequestration should be focused on subsoil sequestration, which was hindered in forestland due to bedrock limitations to soil depth. In these conditions, sequestration in cropland through appropriate management practices is recommended. Content Type Journal Article Category SOILS, SEC 1 • SOIL ORGANIC MATTER DYNAMICS AND NUTRIENT CYCLING • RESEARCH ARTICLE Pages 1-13 DOI 10.1007/s11368-012-0617-7 Authors Juan Albaladejo, Soil and Water Conservation Department, CEBAS-CSIC (Spanish Research Council), Campus de Espinardo, 30100 Murcia, Spain Roque Ortiz, Agricultural Chemistry, Geology and Soil Science Department, Murcia University, Campus de Espinardo, 30100 Murcia, Spain Noelia Garcia-Franco, Soil and Water Conservation Department, CEBAS-CSIC (Spanish Research Council), Campus de Espinardo, 30100 Murcia, Spain Antonio Ruiz Navarro, Soil and Water Conservation Department, CEBAS-CSIC (Spanish Research Council), Campus de Espinardo, 30100 Murcia, Spain Maria Almagro, Soil and Water Conservation Department, CEBAS-CSIC (Spanish Research Council), Campus de Espinardo, 30100 Murcia, Spain Javier Garcia Pintado, Soil and Water Conservation Department, CEBAS-CSIC (Spanish Research Council), Campus de Espinardo, 30100 Murcia, Spain Maria Martínez-Mena, Soil and Water Conservation Department, CEBAS-CSIC (Spanish Research Council), Campus de Espinardo, 30100 Murcia, Spain Journal Journal of Soils and Sediments Online ISSN 1614-7480 Print ISSN 1439-0108