Description: Purpose   At present, many urban areas in Mediterranean climates are coping with water scarcity, facing a growing water demand and a limited conventional water supply. Urban design and planning has so far largely neglected the benefits of rainwater harvesting (RWH) in the context of a sustainable management of this resource. Therefore, the purpose of this study was to identify the most environmentally friendly strategy for rainwater utilization in Mediterranean urban environments of different densities. Materials and methods   The RWH systems modeled integrate the necessary infrastructures for harvesting and using rainwater in newly constructed residential areas. Eight scenarios were defined in terms of diffuse (D) and compact (C) urban models and the tank locations ((1) underground tank, (2) below-roof tank, (3) distributed-over-roof tank, and (4) block tank). The structural and hydraulic sizing of the catchment, storage, and distribution subsystems was taken into account using an average Mediterranean rainfall, the area of the harvesting surfaces, and a constant water demand for laundry. The quantification of environmental impacts was performed through a life cycle assessment, using CML 2001 Baseline method. The necessary materials and processes were considered in each scenario according to the lifecycle stages (i.e., materials, construction, transportation, use, and deconstruction) and subsystems. Results and discussion   The environmental characterization indicated that the best scenario in both urban models is the distributed-over-roof tank (D3, C3), which provided a reduction in impacts compared to the worst scenario of up to 73% in diffuse models and even higher in compact ones, 92% in the most dramatic case. The lower impacts are related to the better distribution of tank weight on the building, reducing the reinforcement requirements, and enabling energy savings. The storage subsystem and the materials stage contributed most significantly to the impacts in both urban models. In the compact density model, the underground-tank scenario (C1) presented the largest impacts in most categories due to its higher energy consumption. Additionally, more favorable environmental results were observed in compact densities than in diffuse ones for the Global Warming Potential category along with higher water efficiencies. Conclusions   The implementation of one particular RWH scenario over another is not irrelevant in drought-stress environments. Selecting the most favorable scenario in the development of newly constructed residential areas provides significant savings in CO 2 emissions in comparison with retrofit strategies. Therefore, urban planning should consider the design of RWH infrastructures using environmental criteria in addition to economic, social, and technological factors, adjusting the design to the potential uses for which the rainwater is intended. Recommendations and perspectives   Additional research is needed to quantify the energy savings associated with the insulation caused by using the tank distributed over the roof. The integration of the economic and social aspects of these infrastructures in the analysis, from a life cycle approach, is necessary for targeting the planning and design of more sustainable cities in an integrated way. Content Type Journal Article Category WATER USE IN LCA Pages 1-18 DOI 10.1007/s11367-011-0330-6 Authors Sara Angrill, Sostenipra (ICTA-IRTA-Inèdit), Institute of Environmental Science and Technology (ICTA), School of Engineering (EE), Universitat Autònoma de Barcelona (UAB), Campus of the UAB, 08193 Bellaterra (Cerdanyola del Vallès), Barcelona, Catalonia, Spain Ramon Farreny, Sostenipra (ICTA-IRTA-Inèdit), Institute of Environmental Science and Technology (ICTA), School of Engineering (EE), Universitat Autònoma de Barcelona (UAB), Campus of the UAB, 08193 Bellaterra (Cerdanyola del Vallès), Barcelona, Catalonia, Spain Carles M. Gasol, Sostenipra (ICTA-IRTA-Inèdit), Institute of Environmental Science and Technology (ICTA), School of Engineering (EE), Universitat Autònoma de Barcelona (UAB), Campus of the UAB, 08193 Bellaterra (Cerdanyola del Vallès), Barcelona, Catalonia, Spain Xavier Gabarrell, Sostenipra (ICTA-IRTA-Inèdit), Institute of Environmental Science and Technology (ICTA), School of Engineering (EE), Universitat Autònoma de Barcelona (UAB), Campus of the UAB, 08193 Bellaterra (Cerdanyola del Vallès), Barcelona, Catalonia, Spain Bernat Viñolas, Department of Geotechnical Engineering and Geosciences, School of Civil Engineering (ETSECCPB), Technical University of Catalonia—Barcelona Tech (UPC), Campus Nord, C/ Jordi Girona 1-3, Building D2, 08034 Barcelona, Catalonia, Spain Alejandro Josa, Department of Geotechnical Engineering and Geosciences, School of Civil Engineering (ETSECCPB), Technical University of Catalonia—Barcelona Tech (UPC), Campus Nord, C/ Jordi Girona 1-3, Building D2, 08034 Barcelona, Catalonia, Spain Joan Rieradevall, Sostenipra (ICTA-IRTA-Inèdit), Institute of Environmental Science and Technology (ICTA), School of Engineering (EE), Universitat Autònoma de Barcelona (UAB), Campus of the UAB, 08193 Bellaterra (Cerdanyola del Vallès), Barcelona, Catalonia, Spain Journal The International Journal of Life Cycle Assessment Online ISSN 1614-7502 Print ISSN 0948-3349

Description: Purpose   Managing declining nutrient use efficiency in crop production has been a global priority to maintain high agricultural productivity with finite non-renewable nutrient resources, in particular phosphorus (P). Rapid spectroscopic methods increase measurement density of soil nutrients and improve the accuracy of rates of additional P inputs. Materials and methods   Soil P was measured by a multi-element energy-dispersive X-ray fluorescence spectroscopic (XRFS) method to estimate the spatial distribution of soil total (XRFS-P) and bioavailable P in a Fluvisol occurring on a 20-ha contiguous area comprised of seven elongated field strips under a wheat–maize rotation near the Quzhou Agricultural Experiment Station in the North China Plain. Results and discussion   Soil XRFS-P was highly variable along the length of the field strips and across the entire area after decades of continuous cultivation. A linear relationship existed between XRFS-P and bicarbonate-extractable P or Mehlich 3-extractable P, allowing a description of the spatial distribution of bioavailable P based on XRFS, in both directions of a two-dimensional grid covering the entire area ( p  〈 0.05). Distinct management zones were identified for more precise placement of additional P. Conclusions   Direct element-specific analysis and a high sample throughput make XRFS an indispensable component of a new approach to sustainably manage P, and other macronutrients of low atomic number Z such as K, Ca, or Cl in production fields, based on their site-specific variations in the soil. Concerning P, this rapid precision approach provides a promising avenue to manage soil P as a regionalized variable while preventing zones of deficiency or surplus P that can affect plant productivity or potential loss from a field, respectively. Content Type Journal Article Pages 1-12 DOI 10.1007/s11368-011-0347-2 Authors Thanh H. Dao, USDA-ARS Environmental Management and ByProducts Utilization Laboratory, BARC-East Bldg. 306, Beltsville, MD 20705, USA Yuxin X. Miao, College of Resources and Environmental Science, China Agricultural University, Beijing, People’s Republic of China Fusuo S. Zhang, College of Resources and Environmental Science, China Agricultural University, Beijing, People’s Republic of China Journal Journal of Soils and Sediments Online ISSN 1614-7480 Print ISSN 1439-0108

Description: Purpose   The aim of this paper is to provide science-based consensus and guidance for health effects modelling in comparative assessments based on human exposure and toxicity. This aim is achieved by (a) describing the USEtox™ exposure and toxicity models representing consensus and recommended modelling practice, (b) identifying key mechanisms influencing human exposure and toxicity effects of chemical emissions, (c) extending substance coverage. Methods   The methods section of this paper contains a detailed documentation of both the human exposure and toxic effects models of USEtox™, to determine impacts on human health per kilogram substance emitted in different compartments. These are considered as scientific consensus and therefore recommended practice for comparative toxic impact assessment. The framework of the exposure model is described in details including the modelling of each exposure pathway considered (i.e. inhalation through air, ingestion through (a) drinking water, (b) agricultural produce, (c) meat and milk, and (d) fish). The calculation of human health effect factors for cancer and non-cancer effects via ingestion and inhalation exposure respectively is described. This section also includes discussions regarding parameterisation and estimation of input data needed, including route-to-route and acute-to-chronic extrapolations. Results and discussion   For most chemicals in USEtox™, inhalation, above-ground agricultural produce, and fish are the important exposure pathways with key driving factors being the compartment and place of emission, partitioning, degradation, bioaccumulation and bioconcentration, and dietary habits of the population. For inhalation, the population density is the key factor driving the intake, thus the importance to differentiate emissions in urban areas, except for very persistent and mobile chemicals that are taken in by the global population independently from their place of emission. The analysis of carcinogenic potency (TD 50 ) when volatile chemicals are administrated to rats and mice by both inhalation and an oral route suggests that results by one route can reasonably be used to represent another route. However, we first identify and mark as interim chemicals for which observed tumours are directly related to a given exposure route (e.g. for nasal or lung, or gastrointestinal cancers) or for which absorbed fraction by inhalation and by oral route differ greatly. Conclusions   A documentation of the human exposure and toxicity models of USEtox™ is provided, and key factors driving the human health characterisation factor are identified. Approaches are proposed to derive human toxic effect factors and expand the number of chemicals in USEtox™, primarily by extrapolating from an oral route to exposure in air (and optionally acute-to-chronic). Some exposure pathways (e.g. indoor inhalation, pesticide residues, dermal exposure) will be included in a later stage. USEtox™ is applicable in various comparative toxicity impact assessments and not limited to LCA. Content Type Journal Article Pages 1-18 DOI 10.1007/s11367-011-0316-4 Authors Ralph K. Rosenbaum, Section for Quantitative Sustainability Assessment, Department of Management Engineering, Technical University of Denmark (DTU), Produktionstorvet, Building 426, 2800 Lyngby, Denmark Mark A. J. Huijbregts, Department of Environmental Science, Radboud University Nijmegen, P.O. Box 9010, 6500 GL, Nijmegen, The Netherlands Andrew D. Henderson, Department of Environmental Health Sciences, School of Public Health, University of Michigan, Ann Arbor, MI, USA Manuele Margni, Department of Chemical Engineering, CIRAIG, École Polytechnique de Montréal, 2900 Édouard-Montpetit, P.O. Box 6079, Stn. Centre-ville, Montréal, Québec H3C 3A7, Canada Thomas E. McKone, University of California Berkeley, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA Dik van de Meent, Department of Environmental Science, Radboud University Nijmegen, P.O. Box 9010, 6500 GL, Nijmegen, The Netherlands Michael Z. Hauschild, Section for Quantitative Sustainability Assessment, Department of Management Engineering, Technical University of Denmark (DTU), Produktionstorvet, Building 426, 2800 Lyngby, Denmark Shanna Shaked, Department of Environmental Health Sciences, School of Public Health, University of Michigan, Ann Arbor, MI, USA Ding Sheng Li, Department of Environmental Health Sciences, School of Public Health, University of Michigan, Ann Arbor, MI, USA Lois S. Gold, University of California Berkeley, and Children’s Hospital Oakland Research Institute (CHORI), Oakland, CA, USA Olivier Jolliet, Department of Environmental Health Sciences, School of Public Health, University of Michigan, Ann Arbor, MI, USA Journal The International Journal of Life Cycle Assessment Online ISSN 1614-7502 Print ISSN 0948-3349

Description: Purpose   In general, pentachloroaniline (PCA) biodechlorination is specific to the conditions of a system; such conditions include the type and concentration of electron donors and oxidizing agents as well as nutrient availability, pH, and temperature. In the bioremediation of contaminated sediments and soil, most researchers have focused on the ability of various electron donors to remove target compounds. However, the amended electron donors and the byproduct of the anoxic/anaerobic systems may cause more environmental impact. Therefore, methods for consistently evaluating the environmental effects of such electron donors and byproducts are highly needed. Accordingly, life cycle assessment (LCA) was carried out to estimate the environmental effect of PCA biodechlorination under acidogenic/methanogenic conditions through laboratory-scale experiments. Four scenarios, intended to assess the influence of electron donors on the environment and develop laboratory experimental research, were compared. In these scenarios, four compounds were used: acetate, lactate, methanol, and glucose + methanol. Materials and methods   The LCA was carried out using IMPACT2002+ to estimate the environmental impact of PCA biodechlorination under acidogenic/methanogenic conditions. To add credibility to the study, sensitivity analysis was also conducted. Results and discussion   In all scenarios, the technologies significantly contributed to respiratory inorganics, global warming, as well as increased the adverse impact of nonrenewable energy on the environment. Specifically, the emissions from the electron donor production processes played an important role in the scenarios. PCA dechlorination and methanogenic processes substantially contributed to the aquatic/terrestrial ecotoxicity and global warming, respectively. Optimizing the concentration of amended electron donors and increasing the population size of dechlorinating microorganisms are highly important in reducing the environmental burden by PCA bioremediation. Conclusions   Results showed that the methanol scenario was the most suitable option determined in this research. In addition, results indicate amended electron donors can cause fewer environmental impacts in carcinogens and noncarcinogens categories. By contrast, the amended electron donors can significantly increase environmental impacts in respiratory inorganics, global warming, and nonrenewable energy categories. Increasing the population size of dechlorinating microorganisms and optimizing the concentration of amended electron donors are highly recommended to reduce adverse environmental impacts. Content Type Journal Article Category LIFE CYCLE MANAGEMENT Pages 1-10 DOI 10.1007/s11367-011-0338-y Authors Jinglan Hong, Shandong Provincial Key Laboratory of Water Pollution Control and Resource Reuse, School of Environmental Science and Engineering, Shandong University, Jinan, 250100 Shandong, People’s Republic of China Xiangzhi Li, Shandong University School of Medicine, Jinan, 250012 Shandong, People’s Republic of China Journal The International Journal of Life Cycle Assessment Online ISSN 1614-7502 Print ISSN 0948-3349