In:
Chimica Techno Acta, Ural Federal University, Vol. 3, No. 1 ( 2016-03-15), p. 68-84
Abstract:
This work is a continuation of the article "Surface reactions with participation of oxides of molybdenum and tungsten", published in the previous issue of the journal. The influence of the electric field and the pressure of oxygen in the gas phase on the rate of surface reactions for the synthesis of molybdates of manganese and copper were investigated. It’s found that for the synthesis reaction of molybdate of copper the nature of the dependency of the rate of synthesis and rate of surface reactions from the external parameters are the same, indicating the crucial contribution of surface diffusion to the reactive mass transfer. For the synthesis reaction of molybdate of manganese the dependences of the rate of synthesis and of rate of surface reactions by external parameters differ, indicating that for this reaction, surface diffusion isn’t the main mechanism of mass transfer.
Type of Medium:
Online Resource
ISSN:
2411-1414
,
2409-5613
Uniform Title:
Поверхностные реакции с участием оксидов молибдена и вольфрама: влияние внешних факторов
DOI:
10.15826/chimtech.2016.3.1.006
Language:
Russian
Publisher:
Ural Federal University
Publication Date:
2016
detail.hit.zdb_id:
2912521-2
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