In:
Canadian Journal of Chemistry, Canadian Science Publishing, Vol. 54, No. 10 ( 1976-05-15), p. 1590-1598
Abstract:
The thermal isomerization of 2-vinylaziridines, variously substituted on the ring and the double bond, has been studied. The nature of the products formed depends on the nature of the substituents in positions 1 and 3. If the ring carbon-3 carries a phenyl substituent, the thermolysis yields, in most cases, a Δ-2-pyrroline. With unsubstituted or 3-alkylaziridines the reaction proceeds, depending on the nature of the substituent on the nitrogen, either to an ethylene imine or to a mixture of Δ-2- and Δ-3-pyrrolines. Mechanisms to interpret the experimental results are proposed. [Journal translation]
Type of Medium:
Online Resource
ISSN:
0008-4042
,
1480-3291
Language:
French
Publisher:
Canadian Science Publishing
Publication Date:
1976
detail.hit.zdb_id:
1482256-8
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