Abstract
Using the chemical composition of snow and ice of a central Greenland ice core, we have investigated changes in atmospheric HNO3 chemistry following the large volcanic eruptions of Laki (1783), Tambora (1815) and Katmai (1912). The concentration of several cations and anions, including SO 2−4 and NO −3 , were measured using ion chromatography. We found that following those eruptions, the ratio of the concentration of NO −3 deposited during winter to that deposited during summer was significantly higher than during nonvolcanic periods. Although we cannot rule out that this pattern originates from snow pack effects, we propose that increased concentrations of volcanic H2SO4 particles in the stratosphere may have favored condensation and removal of HNO3 from the stratosphere during Arctic winter. In addition, this pattern might have been enhanced by slower formation of HNO3 during summer, caused by direct consumption of OH through oxidation of volcanic SO2.
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References
Alley, R. B. and Koci, B. R., 1988, Ice-core analysis at Site A, Greenland: Preliminary results,Ann. Glaciol. 10, 45–54.
Arnold, F., Bührke, T., and Qiu, S., 1990, Evidence for stratospheric ozone depleting heterogeneous chemistry on volcanic aerosols from El Chichon,Nature 348, 49–50.
Brune, W. H., Anderson, J. G., Toohey D. W., Fahey, D. W., Kawa, S. R., Jones, R. L., McKenna, D. S., and Poole, L. R., 1991, The potential for ozone depletion in the Arctic polar stratosphere,Science 252, 1260–1266.
Clausen, H. B., Gundestrup, N. S., and Johnsen, S. J., 1988, Glaciological investigations in the Crete area, central Greenland: A search for a new deep-drilling site,Ann. Glaciol. 10, 7–11.
Clausen, H. B. and Langway, C. C. J., 1989, The ionic deposits in polar ice cores, in H. Oeschger and C. C. Langway (eds),The Environmental Record in Glaciers and Ice Sheets, Wiley, New York, pp. 225–247.
Fiacco, R. J., 1991, Microparticles as a paleovolcanic indicator in the 1989 GISP2 firn and ice core, Master's thesis, University of New Hampshire.
Graedel, T. E., 1978,Chemical Compounds in the Atmosphere, Academic Press, New York.
Hildreth, W., 1983, The compositionally zoned eruption of 1912 in the Valley of Ten Thousand Smokes, Katmai National Park, Alaska,J. Volcanol. Geotherm. Res. 18, 1–56.
Hofmann, D. and Solomons, S., 1989, Ozone destruction through heterogeneous chemistry following the eruption of El Chicon,J. Geophys. Res. 94, 5029–5041.
Hofmann, D., 1992, An investigation of heterogeneous chemical effects of the Pinatubo eruption on stratospheric ozone over Colorado, Wyoming, Hawaii and Antarctica,Abstract Proceeding the Chapman Conference on Climate and Volcanism, Hilo, Hawaii.
Jacob, D. J., Wofsy, S. C., Bakwin, P. S., Fan, S. M., Harriss, R. C., Talbot, R. W., Bradshaw, J. D., Sandholm, S. T., Singh, H. B., Gregory, G. L., Sachse, G. W., Shipman, M., Blake, D. R., and Fitzjerrald, D. R., 1992, Summertime photochemistry of the Arctic troposphere,J. Geophys. Res. 97 (D15), 16,421–16,431.
Jones, H. G. and Laberge, C., 1990, Nitrate losses from snow strata in snowpack under cold (<0°) conditions,EOS 69, 1202.
Laird, C. M., Zeller, E. J., and Dreschoff, G. A. N., 1987, Nitrate variability in South Pole ice sequences and fossil surface effects,Antarc. J. US 22, 80–83.
Laj, P., Drummey, S., Spencer, M. J., Palais, J. M., and Sigurdsson, H., 1990, H2O2 depletion in a Greenland Ice-Core: implication for oxidation of volcanic SO2,Nature 346, 45–48.
Laj, P., Palais, J. M., and Sigurdsson, H., 1992, Changing sources of impurities to the Greenland ice sheet,Atmos. Environ. 26A, 2627–2640.
Legrand, M. and Kirchner, S., 1990, Origins and variations of nitrate in the south polar snow,J. Geophys. Res. 95, 3493–3507.
Legrand, M., De Angelis, M., Staffelbach, T., Neftel, A., and Stauffer, B., 1991, Large perturbations of ammonium and organic acids content in the Summit-Greenland ice core. Fingerprints from forest fires?Geophys. Res. Lett. 19(5), 473–475.
Lightfoot, P. D., Cox, R. A., Crowley, J. N., Destriau, M., Hayman, G. D., Jenkin, M. E., Moortgat, G. K., and Zabel, F., 1992, Organic peroxy radicals: kinetics, spectroscopy and tropospheric chemistry,Atmos. Environ. 26A(10), 1805–1964.
Molina, L. T. and Molina, M. J., 1987, Production of Cl2O2 from the self reaction of the ClO radical,J. Phys. Chem. 91, 433–436.
Moller, D., 1990, The Na/Cl ratio in rainwater and the sea-salt chloride cycle,Tellus 42B, 254–262.
Mozurkewich, M. and Calvert, J. G., 1988, Reaction probability of N2O5 on aqueous aerosols,J. Geophys. Res. 93, 15,889–15,896.
Neubauer, J. and Heumann, K. G., 1988, Nitrate trace determination in snow and firn core samples of ice sheles at the Weddel sea, Antarctica,Atmos. Environ. 22, 537–545.
Palais, J. M. and Sigurdsson, H., 1989, Petrologic evidence of volatile emissions from major historic and pre-historic volcanic eruptions, in A. G. U. Monograph (ed.),Understanding Climate Change, pp. 31–53.
Pinto, J. P., Turco, R. P., and Toon, O. B., 1989, Self limiting physical and chemical effects in volcanic eruption clouds,J. Geophys. Res. 94, 11,165–11,174.
Pitari, G. and Visconti, G., 1991, Odd nitrogen removal on background sulfate aerosols: implication for the ozone hole,Geophys. Res. Lett. 18(10), 1853–1856.
Pollack, J. B., Toon, O. B., Sagan, C., Summers, A., Baldwin, B., and VanCamp, W., 1976, Volcanic explosions and climatic change: a theoretical assessment,J. Geophys. Res. 81, 1071–1083.
Rampino, M. R., Self, S., and Stothers, R. B., 1985, Climatic effects of volcanic eruptions,Nature 313, 272–274.
Rodriguez, J. M., Ko, M. K. W., and Sze, N. D., 1991, Role of heterogeneous conversion of N2O5 on sulphate aerosols in global ozone losses,Nature 352, 134–137.
Russell, A. G., McRae, G. J., and Cass, G. R., 1985, The dynamics of nitric acid production and the fate of nitrogen oxides,Atmos. Environ. 19, 893–903.
Sigg, A. and Neftel, A., 1991, Summit ice-core provides a 700-year record of atmospheric hydrogen peroxide,Nature 351, 557–559.
Sigurdsson, H., 1982, The 1783 Laki eruption: volcanic pollution and climate,EOS 63, 601–602.
Sigurdsson, H. and Carey, S., 1989, Plinian and co-ignimbrite tephra fall from the 1815 eruption of Tambora volcano,Bull. Vol. 51, 243–270.
Sigurdsson, H., 1990, Evidence of volcanic loading of the atmosphere and climate response,Global and Planetary Change 3, 601–602.
Spencer, M. J., Lyons, W. B., Twickler, M. S., and Mayewski, P. A., 1985, Contamination control for polar ice core samples,EOS 66, 895–896.
Stockwell, W. R. and Calvert, J. G., 1983, The mechanism of the HO-SO2 reaction,Atmos. Environ. 17, 2231–2235.
Stothers, R. B., Wolff, J. A., Self, S., and Rampino, M. R., 1986, Basaltic fissure eruptions, plume heights, and atmospheric aerosols,Geophys. Res. Let. 13, 725–728.
Toon, O. B., Turco, R. P., and Hamill, P., 1990, Denitrification mechanisms in the polar stratosphere,Geophys. Res. Let. 17, 445–448.
Tuazon, E. C., Atkinson, R., Plum, C. N., Winer, A. M., and Pitts J. N. J., 1983, The reaction of gas phase N2O5 with water vapor,Geophys. Res. Lett. 10, 953–956.
Warneck, P., 1988,Chemistry of the Natural Atmosphere, Academic Press, New York.
Whitlow, S., Mayewski, P. A., and Dibb, J. E. A., 1992, Comparison of major chemical species seasonal concentration and accumulation at the South Pole and Summit, Greenland,Atmos. Environ. 26A(11), 2045–2054.
Wofsy, S. C., Salawitch, R. J., Yatteau, J. H., McElroy, M. B., Gandrud, B. W., Dye, J. E., and Baumgardner, D., 1990, Condensation of HNO3 on falling ice particles: mechanism for denitrification of the Polar stratosphere,Geophys. Res. Lett. 17(4), 449–452.
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Laj, P., Palais, J.M., Gardner, J.E. et al. Modified HNO3 seasonality in volcanic layers of a polar ice core: Snow-pack effect or photochemical perturbation?. J Atmos Chem 16, 219–230 (1993). https://doi.org/10.1007/BF00696897
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DOI: https://doi.org/10.1007/BF00696897