Mixed-valent palladium(iv/ii)-oxoanion, [PdIVO6Pd II6((CH3)2AsO2)6]2−†
Xiang
Ma, 
a
Saurav
Bhattacharya,
‡a
Talha
Nisar,
a
Veit
Wagner,
a
Nikolai
Kuhnert
a
and
Ulrich
Kortz
*a
a
Saurav
Bhattacharya,
‡a
Talha
Nisar,
a
Veit
Wagner,
a
Nikolai
Kuhnert
a
and
Ulrich
Kortz
*a
Abstract
We report on the first example of a PdIV-containing polyoxopalladate(II). The discrete mixed-valent polyoxopalladate(IV/II), [PdIVPdII6O6((CH3)2AsO2)6]2−, comprising a central PdIV ion that is surrounded by a six-membered PdII-oxo ring capped by six dimethylarsinate groups, was synthesized and structurally characterized in the solid state, in solution and in the gas phase by multiple analytical techniques.
![Graphical abstract: Mixed-valent palladium(iv/ii)-oxoanion, [PdIVO6PdII6((CH3)2AsO2)6]2−](/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=D2CC05699B&imageInfo.ImageIdentifier.Year=2023)
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