Abstract
Detrital magnetic materials within cave stalagmitic formations, e.g., haematite or magnetite, carry remanence whose vector is of value in dating. Magnetometry measurements on a particular haematite‐bearing sample reveal that remanence was substantially restored and/or conserved on rewarming after cooling below the Morin transition temperature. Mössbauer measurements indicate the presence of two types of haematite, distinguished primarily by particle size. The majority is small in size, partially exhibiting superparamagnetism, and does not undergo a Morin transition above liquid nitrogen temperature. Superparamagnetic goethite is the second major component. Mine haematite samples of surface location with different color and mineralogical composition have also been studied. Possible relations between the mineralogical composition of the mine samples and detrital stalagmitic magnetic material, the modifications and the origin of this mineralization are discussed. Special attention is paid to the “irreversible” Morin transition in large enough (>20 nm) haematite particles and the possible loss of natural remanent magnetization and hence of palaeomagnetic records.
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Rusanov, V., Gilson, R., Lougear, A. et al. Mössbauer, magnetic, X‐ray fluorescence and transmission electron microscopy study of natural magnetic materials from speleothems: haematite and the Morin transition. Hyperfine Interactions 128, 353–373 (2000). https://doi.org/10.1023/A:1012668623559
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DOI: https://doi.org/10.1023/A:1012668623559