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Short Side Chain Aquivion Perfluorinated Sulfonated Proton-Conductive Membranes: Transport and Mechanical Properties

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Abstract

Data on the water uptake, proton conductivity, diffusion permeability, cation transport selectivity, and mechanical properties of short side chain Aquivion sulfonated perfluoropolymer membranes with an equivalent weight of 870 and 965 have been described. Properties of the membranes have been compared with those of a long side chain Nafion 212 membrane (equivalent weight of 1100). An increase in the equivalent weight leads to an increase in the sorption exchange capacity and water uptake of the membranes and a decrease in their proton conductivity. The conductivity of the Aquivion membrane with an equivalent weight of 870 is 1.4–1.5 times higher than that of the Nafion 212 membrane; it reaches 13.6 mS/cm in contact with water and 1.0 mS/cm at a relative humidity of 32% at 25°C. Diffusion permeability and cation transport selectivity exhibit a nonmonotonic dependence on the equivalent weight of the material. The lowest diffusion permeability, the highest Na+ cation transport selectivity (99.5%), and the best mechanical properties have been found for the Aquivion membrane with an equivalent weight of 965, which is characterized by the highest degree of crystallinity.

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References

  1. S. J. Peighambardoust, S. Rowshanzamir, and M. Amjadi, Int. J. Hydrogen Energy 35, 9349 (2010).

    Article  CAS  Google Scholar 

  2. S. Bose, T. Kuila, T. X. Hien Nguyen, et al., Prog. Polym. Sci. 36, 813 (2011).

    Article  CAS  Google Scholar 

  3. E. Yu. Safronova and A. B. Yaroslavtsev, Pet. Chem. 56, 281 (2016).

    Article  CAS  Google Scholar 

  4. K. A. Mauritz and R. B. Moore, Chem. Rev. 104, 4535 (2004).

    Article  CAS  Google Scholar 

  5. Deuk Ju Kim, Min Jae Jo, and Sang Yong Nam, J. Ind. Eng. Chem. 21, 36 (2015).

    Article  CAS  Google Scholar 

  6. C. M. Branco, A. El-kharouf, and S. Du, in Reference Module in Materials Science and Materials Engineering., Ed. by S. Hashmi (Elsevier, 2017). doi 10.1016/b978-0-12-803581-8.09261-4

  7. A. B. Yaroslavtsev, Russ. Chem. Rev. 78 (11), 1013 (2009).

    Article  CAS  Google Scholar 

  8. G. Pourcelly, Pet. Chem. 51, 480 (2011).

    Article  CAS  Google Scholar 

  9. G. Alberti, R. Narducci, and M. Sganappa, J. Power Sources 178, 575 (2008).

    Article  CAS  Google Scholar 

  10. E. Safronova, D. Safronov, A. Lysova, et al., Sens. Actuators B 240, 1016 (2017).

    Article  CAS  Google Scholar 

  11. B. P. Tripathi and V. K. Shahi, Prog. Polym. Sci. 36, 945 (2011).

    Article  CAS  Google Scholar 

  12. E. Yu. Safronova and A. B. Yaroslavtsev, Solid State Ionics 221, 6 (2012).

    Article  CAS  Google Scholar 

  13. V. D. Noto, N. Boaretto, E. Negro, et al., Int. J. Hydrogen Energy 37, 6215 (2012).

    Article  Google Scholar 

  14. H. Strathmann, A. Grabowski, and G. Eigenberger, J. Ind. Eng. Chem. Res. 52, 10364 (2013).

    Article  CAS  Google Scholar 

  15. B. R. Matos, R. A. Isidoro, E. I. Santiago, et al., Int. J. Hydrogen Energy 40, 1859 (2015).

    Article  CAS  Google Scholar 

  16. E. Gerasimova, E. Safronova, A. Ukshe, et al., Chem. Eng. J. 305, 121 (2016).

    Article  CAS  Google Scholar 

  17. I. A. Prikhno, E. Yu. Safronova, and A. B. Yaroslavtsev, Int. J. Hydrogen Energy 41, 15585 (2016).

    Article  CAS  Google Scholar 

  18. E. Yu. Safronova, I. A. Stenina, and A. B. Yaroslavtsev, Pet. Chem. 57, 299 (2017).

    Article  CAS  Google Scholar 

  19. C. C. Ke, X. J. Li, S. G. Qu, et al., Polym. Adv. Technol. 23, 92 (2012).

    Article  CAS  Google Scholar 

  20. H. Tang, Z. Wan, M. Pan, and S. P. Jiang, Electrochem. Commun. 9, 2003 (2007).

    Article  CAS  Google Scholar 

  21. A. D’Epifanio, B. Mecher, E. Fabbri, et al., J. Electrochem. Soc. 154, B1148 (2007).

    Article  Google Scholar 

  22. K. D. Kreuer, M. Schuster, B. Obliers, et al., J. Power Sources 178, 499 (2008).

    Article  CAS  Google Scholar 

  23. P. Xiao, J. Li, H. Tang, et al., J. Membr. Sci. 442, 65 (2013).

    Article  CAS  Google Scholar 

  24. J. Li, M. Pan, and H. Tang, RSC Adv. 4, 3944 (2014).

    Article  CAS  Google Scholar 

  25. N. Berezina, S. Timofeev, and N. Kononenko, J. Membr. Sci. 209, 509 (2002).

    Article  CAS  Google Scholar 

  26. G. Alberti, R. Narducci, and M. Sganappa, J. Power Sources 178, 575 (2008).

    Article  CAS  Google Scholar 

  27. R. Kuwertz, C. Kirstein, T. Turek, and U. Kunz, J. Membr. Sci. 500, 225 (2016).

    Article  CAS  Google Scholar 

  28. A. Skulimowska, M. Dupont, M. Zaton, et al., Int. J. Hydrogen Energy 39, 6307 (2014).

    Article  CAS  Google Scholar 

  29. M. Amirinejad, S. S. Madaeni, M. A. Navarra, et al., J. Power Sources 196, 988 (2011).

    Article  CAS  Google Scholar 

  30. M. Geise, H. J. Cassady, D. R. Paul, et al., Phys. Chem. Chem. Phys. 16, 21673 (2014).

    Article  CAS  Google Scholar 

  31. V. I. Volkov, E. V. Volkov, S. V. Timofeev, et al., Russ. J. Inorg. Chem. 55, 315 (2010).

    Article  CAS  Google Scholar 

  32. V. I. Roldugin and L. V. Karpenko-Jereb, Colloid J. 78, 795 (2016).

    Article  Google Scholar 

  33. A. B. Yaroslavtsev and V. V. Nikonenko, Nanotechnol. Russ. 4, 137 (2009).

    Article  Google Scholar 

  34. G. Gebel and R. B. Moore, Macromolecules 33, 4850 (2000).

    Article  CAS  Google Scholar 

  35. K. D. Kreuer, M. Schuster, B. Obliers, et al., J. Power Sources 178, 499 (2008).

    Article  CAS  Google Scholar 

  36. M. K. Mistry, N. R. Choudhury, N. K. Dutta, and R. Knott, Langmuir 26, 19073 (2010).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russia

    E. Yu. Safronova, A. K. Osipov & A. B. Yaroslavtsev

  2. Department of Chemistry, Moscow State University, Moscow, 119991, Russia

    A. K. Osipov & A. B. Yaroslavtsev

  3. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia

    A. B. Yaroslavtsev

Authors
  1. E. Yu. Safronova
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  2. A. K. Osipov
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  3. A. B. Yaroslavtsev
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Correspondence to E. Yu. Safronova.

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Original Russian Text © E.Yu. Safronova, A.K. Osipov, A.B. Yaroslavtsev, 2018, published in Membrany i Membrannye Tekhnologii, 2018, Vol. 8, No. 1, pp. 34–41.

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Safronova, E.Y., Osipov, A.K. & Yaroslavtsev, A.B. Short Side Chain Aquivion Perfluorinated Sulfonated Proton-Conductive Membranes: Transport and Mechanical Properties. Pet. Chem. 58, 130–136 (2018). https://doi.org/10.1134/S0965544118020044

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