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Amides of heterocyclic carboxylic acids as novel extractants for high-level waste treatment

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Radiochemistry Aims and scope

Abstract

Extraction properties of various heterocyclic carboxylic acid amides are considered. The extraction properties of heterocyclic dicarboxylic acid diamides are determined by two major factors: diamide structure and kind of diluent. Among heterocyclic (di)carboxylic acid amides and diamides, the most promising extractants for separating actinides and lanthanides are tri- and tetradentate extractants: diamides of dipicolinic, bipyridinedicarboxylic, and phenanthrolinedicarboxylic acids, which can be used for recovering metals from acid solutions.

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Authors and Affiliations

  1. Khlopin Radium Institute, 2-i Murinskii pr. 28, St. Petersburg, 194021, Russia

    M. Yu. Alyapyshev, V. A. Babain & L. I. Tkachenko

  2. Laboratory of Artificial Sensor Systems, St. Petersburg National Research University of Information Technologies, Mechanics, and Optics, Kronverkskii pr. 49, St. Petersburg, 197101, Russia

    M. Yu. Alyapyshev & V. A. Babain

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  1. M. Yu. Alyapyshev
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  2. V. A. Babain
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  3. L. I. Tkachenko
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Correspondence to M. Yu. Alyapyshev.

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Original Russian Text © M.Yu. Alyapyshev, V.A. Babain, L.I. Tkachenko, 2014, published in Radiokhimiya, 2014, Vol. 56, No. 6, pp. 481–489.

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Alyapyshev, M.Y., Babain, V.A. & Tkachenko, L.I. Amides of heterocyclic carboxylic acids as novel extractants for high-level waste treatment. Radiochemistry 56, 565–574 (2014). https://doi.org/10.1134/S1066362214060010

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  • DOI: https://doi.org/10.1134/S1066362214060010

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