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Profe, Jörn; Wacha, Lara; Frechen, Manfred; Ohlendorf, Christian; Zolitschka, Bernd (2017): XRF, Carbon and CaCO3 data from the profiles Bok N, Bok O, Bok P on the Island of Susak [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.879353, Supplement to: Profe, J et al. (2018): XRF scanning of discrete samples – A chemostratigraphic approach exemplified for loess-paleosol sequences from the Island of Susak, Croatia. Quaternary International, 494, 34-51, https://doi.org/10.1016/j.quaint.2018.05.006

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Abstract:
X-ray fluorescence (XRF) scanning of discrete samples provides a time- and cost-efficient alternative to conventional geochemical analyses of discretely sampled paleoenvironmental archives. Loess-paleosol sequences (LPS) as complex terrestrial archives are thus predestinated for benchmarking this new application of the well-established XRF scanning technology. Stratigraphically incomplete outcrops, like those on the Island of Susak (Croatia), are unique paleoenvironmental archives at least for the penultimate and last interglacial/glacial cycles and provide ideal test sites. Available proxy data from previous investigations on Susak ensure validation of conclusions drawn from XRF scanning-derived data.
Three representative profiles were studied to examine the potential of XRF scanning-derived element ratios as proxy for environmental processes: (1) Ca/Sr for the strength of ubiquitously present secondary calcification; (2) Rb/K for the intensity of weathering; (3) Ti/Al and Ti/Zr for changes in wind speed with Zr being additionally indicative for sediment recycling; (4) Si/Al for changes in grain-size; and (5) Br and Cl as proxies for sea spray. Furthermore, we established a multivariate statistics-based chemostratigraphy to facilitate profile correlation and to improve lithostratigraphic characterization. In conclusion, this study demonstrates that XRF scanning of discrete samples from LPS is a valuable tool for paleoenvironmental reconstruction.
Coverage:
Median Latitude: 44.508933 * Median Longitude: 14.315867 * South-bound Latitude: 44.507800 * West-bound Longitude: 14.314500 * North-bound Latitude: 44.510200 * East-bound Longitude: 14.317600
Minimum SECTION, height: 0.00 m * Maximum SECTION, height: 3.24 m
Event(s):
Bok_N * Latitude: 44.510200 * Longitude: 14.314500
Bok_O * Latitude: 44.507800 * Longitude: 14.317600
Bok_P * Latitude: 44.508800 * Longitude: 14.315500
Comment:
GEOPOLAR, Institute of Geography, Bremen: Pilot study for the geochemical characterization of loess-palaeosoil sequences (Project S3) - German Research Foundation (DFG)
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
1Event labelEventProfe, Jörn
2Latitude of eventLatitudeProfe, Jörn
3Longitude of eventLongitudeProfe, Jörn
4SECTION, heightSectionmProfe, JörnGeocode
5Lithology/composition/faciesLithologyWacha, Lara
6Carbon, totalTC%Profe, Jörn
7Carbon, organic, totalTOC%Profe, Jörn
8Carbon, inorganic, totalTIC%Profe, Jörn
9Calcium carbonateCaCO3%Profe, Jörn
10Mean squared errorMSEProfe, JörnX-ray fluorescence ITRAX core scanner, Mo-tube 30kV 30mA 100s, Bremen
11AluminiumAlctsProfe, JörnX-ray fluorescence ITRAX core scanner, Mo-tube 30kV 30mA 100s, Bremen
12SiliconSictsProfe, JörnX-ray fluorescence ITRAX core scanner, Mo-tube 30kV 30mA 100s, Bremen
13ChlorineClctsProfe, JörnX-ray fluorescence ITRAX core scanner, Mo-tube 30kV 30mA 100s, Bremen
14PotassiumKctsProfe, JörnX-ray fluorescence ITRAX core scanner, Mo-tube 30kV 30mA 100s, Bremen
15CalciumCactsProfe, JörnX-ray fluorescence ITRAX core scanner, Mo-tube 30kV 30mA 100s, Bremen
16TitaniumTictsProfe, JörnX-ray fluorescence ITRAX core scanner, Mo-tube 30kV 30mA 100s, Bremen
17ManganeseMnctsProfe, JörnX-ray fluorescence ITRAX core scanner, Mo-tube 30kV 30mA 100s, Bremen
18IronFectsProfe, JörnX-ray fluorescence ITRAX core scanner, Mo-tube 30kV 30mA 100s, Bremen
19BromineBrctsProfe, JörnX-ray fluorescence ITRAX core scanner, Mo-tube 30kV 30mA 100s, Bremen
20RubidiumRbctsProfe, JörnX-ray fluorescence ITRAX core scanner, Mo-tube 30kV 30mA 100s, Bremen
21StrontiumSrctsProfe, JörnX-ray fluorescence ITRAX core scanner, Mo-tube 30kV 30mA 100s, Bremen
22ZirconiumZrctsProfe, JörnX-ray fluorescence ITRAX core scanner, Mo-tube 30kV 30mA 100s, Bremen
23BariumBactsProfe, JörnX-ray fluorescence ITRAX core scanner, Mo-tube 30kV 30mA 100s, Bremen
24IncoherenceicohctsProfe, JörnX-ray fluorescence ITRAX core scanner, Mo-tube 30kV 30mA 100s, Bremen
25CoherencecohctsProfe, JörnX-ray fluorescence ITRAX core scanner, Mo-tube 30kV 30mA 100s, Bremen
26Mean squared errorMSEProfe, JörnX-ray fluorescence ITRAX core scanner, Cr-tube 30kV 40mA 100s, Bremen
27AluminiumAlctsProfe, JörnX-ray fluorescence ITRAX core scanner, Cr-tube 30kV 40mA 100s, Bremen
28SiliconSictsProfe, JörnX-ray fluorescence ITRAX core scanner, Cr-tube 30kV 40mA 100s, Bremen
29ChlorineClctsProfe, JörnX-ray fluorescence ITRAX core scanner, Cr-tube 30kV 40mA 100s, Bremen
30PotassiumKctsProfe, JörnX-ray fluorescence ITRAX core scanner, Cr-tube 30kV 40mA 100s, Bremen
31CalciumCactsProfe, JörnX-ray fluorescence ITRAX core scanner, Cr-tube 30kV 40mA 100s, Bremen
32TitaniumTictsProfe, JörnX-ray fluorescence ITRAX core scanner, Cr-tube 30kV 40mA 100s, Bremen
33ManganeseMnctsProfe, JörnX-ray fluorescence ITRAX core scanner, Cr-tube 30kV 40mA 100s, Bremen
34IronFectsProfe, JörnX-ray fluorescence ITRAX core scanner, Cr-tube 30kV 40mA 100s, Bremen
35BromineBrctsProfe, JörnX-ray fluorescence ITRAX core scanner, Cr-tube 30kV 40mA 100s, Bremen
36RubidiumRbctsProfe, JörnX-ray fluorescence ITRAX core scanner, Cr-tube 30kV 40mA 100s, Bremen
37StrontiumSrctsProfe, JörnX-ray fluorescence ITRAX core scanner, Cr-tube 30kV 40mA 100s, Bremen
38ZirconiumZrctsProfe, JörnX-ray fluorescence ITRAX core scanner, Cr-tube 30kV 40mA 100s, Bremen
39BariumBactsProfe, JörnX-ray fluorescence ITRAX core scanner, Cr-tube 30kV 40mA 100s, Bremen
40IncoherenceicohctsProfe, JörnX-ray fluorescence ITRAX core scanner, Cr-tube 30kV 40mA 100s, Bremen
41CoherencecohctsProfe, JörnX-ray fluorescence ITRAX core scanner, Cr-tube 30kV 40mA 100s, Bremen
42log-Calcium/Strontium ratiolog(Ca/Sr)Profe, JörnX-ray fluorescence ITRAX core scanner, Mo-tube 30kV 30mA 100s, Bremen
43log-Rubidium/Strontium ratiolog(Rb/Sr)Profe, JörnX-ray fluorescence ITRAX core scanner, Mo-tube 30kV 30mA 100s, Bremen
44log-Barium/Strontium ratiolog(Ba/Sr)Profe, JörnX-ray fluorescence ITRAX core scanner, Mo-tube 30kV 30mA 100s, Bremen
45log-Rubidium/Potassium ratiolog(Rb/K)Profe, JörnX-ray fluorescence ITRAX core scanner, Mo-tube 30kV 30mA 100s, Bremen
46log-Titanium/Zirconium ratiolog(Ti/Zr)Profe, JörnX-ray fluorescence ITRAX core scanner, Mo-tube 30kV 30mA 100s, Bremen
47log-Titanium/Aluminium ratiolog(Ti/Al)Profe, JörnX-ray fluorescence ITRAX core scanner, Cr-tube 30kV 40mA 100s, Bremen
48log-Silicon/Aluminium ratiolog(Si/Al)Profe, JörnX-ray fluorescence ITRAX core scanner, Cr-tube 30kV 40mA 100s, Bremen
49log-Zirconium/Rubidium ratiolog(Zr/Rb)Profe, JörnX-ray fluorescence ITRAX core scanner, Mo-tube 30kV 30mA 100s, Bremen
50log-Iron/Manganese ratiolog(Fe/Mn)Profe, JörnX-ray fluorescence ITRAX core scanner, Mo-tube 30kV 30mA 100s, Bremen
51BromineBrmg/kgProfe, Jörnoriginal in ppm
52Confidence intervalCIProfe, Jörn95%
53ChlorineClmg/kgProfe, Jörnoriginal in ppm
54Confidence intervalCIProfe, Jörn95%
55Chlorine/Bromine ratioCl/BrProfe, Jörn
Size:
18799 data points

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