Isotopic Compositions (Li‐B‐Si‐O‐Mg‐Sr‐Nd‐Hf‐Pb) and Fe2+/ΣFe Ratios of Three 
Synthetic Andesite Glass Reference Materials (ARM‐1, ARM‐2, ARM‐3)

Wu, Shitou; Yang, Yueheng; Jochum, Klaus Peter; Romer, R. L.; Glodny, J.; Savov, Ivan P.; Agostini, Samuele; De Hoog, Jan C.M.; Peters, Stefan T.M.; Kronz, Andreas; Zhang, Chao; Bao, Zhian; Wang, Xiaojun; Li, Youlian; Tang, Guoqiang; Feng, Lianjun; Yu, Huimin; Li, Zhenxin; Zhang, Le; Lin, Jie; Zeng, Yuan; Xu, Chunxue; Wang, Yaping; Cui, Zhu; Deng, Li; Xiao, Jun; Liu, Yanhong; Xue, Dingshuai; Zhang, Di; Jia, Lihui; Wang, Hao; Xu, Lei; Huang, Chao; Xie, Liewen; Pack, Andreas; Wörner, Gerhard; He, Maoyong; Li, Chaofeng; Yuan, Honglin; Huang, Fang; Li, Qiuli; Yang, Jinhui; Li, Xianhua; Wu, Fuyuan

doi:10.1111/ggr.12399

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Isotopic Compositions (Li‐B‐Si‐O‐Mg‐Sr‐Nd‐Hf‐Pb) and Fe2+/ΣFe Ratios of Three Synthetic Andesite Glass Reference Materials (ARM‐1, ARM‐2, ARM‐3)

Authors

Wu, Shitou
External Organizations;

Yang, Yueheng
External Organizations;

Jochum, Klaus Peter
External Organizations;

/persons/resource/romer

Romer, R. L.
3.1 Inorganic and Isotope Geochemistry, 3.0 Geochemistry, Departments, GFZ Publication Database, Deutsches GeoForschungsZentrum;

/persons/resource/glodnyj

Glodny, J.
3.1 Inorganic and Isotope Geochemistry, 3.0 Geochemistry, Departments, GFZ Publication Database, Deutsches GeoForschungsZentrum;

Savov, Ivan P.
External Organizations;

Agostini, Samuele
External Organizations;

De Hoog, Jan C.M.
External Organizations;

Peters, Stefan T.M.
External Organizations;

Kronz, Andreas
External Organizations;

Zhang, Chao
External Organizations;

Bao, Zhian
External Organizations;

Wang, Xiaojun
External Organizations;

Li, Youlian
External Organizations;

Tang, Guoqiang
External Organizations;

Feng, Lianjun
External Organizations;

Yu, Huimin
External Organizations;

Li, Zhenxin
External Organizations;

Zhang, Le
External Organizations;

Lin, Jie
External Organizations;

Zeng, Yuan
External Organizations;

Xu, Chunxue
External Organizations;

Wang, Yaping
External Organizations;

Cui, Zhu
External Organizations;

Deng, Li
External Organizations;

Xiao, Jun
External Organizations;

Liu, Yanhong
External Organizations;

Xue, Dingshuai
External Organizations;

Zhang, Di
External Organizations;

Jia, Lihui
External Organizations;

Wang, Hao
External Organizations;

Xu, Lei
External Organizations;

Huang, Chao
External Organizations;

Xie, Liewen
External Organizations;

Pack, Andreas
External Organizations;

Wörner, Gerhard
External Organizations;

He, Maoyong
External Organizations;

Li, Chaofeng
External Organizations;

Yuan, Honglin
External Organizations;

Huang, Fang
External Organizations;

Li, Qiuli
External Organizations;

Yang, Jinhui
External Organizations;

Li, Xianhua
External Organizations;

Wu, Fuyuan
External Organizations;

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Citation

Wu, S., Yang, Y., Jochum, K. P., Romer, R. L., Glodny, J., Savov, I. P., Agostini, S., De Hoog, J. C., Peters, S. T., Kronz, A., Zhang, C., Bao, Z., Wang, X., Li, Y., Tang, G., Feng, L., Yu, H., Li, Z., Zhang, L., Lin, J., Zeng, Y., Xu, C., Wang, Y., Cui, Z., Deng, L., Xiao, J., Liu, Y., Xue, D., Zhang, D., Jia, L., Wang, H., Xu, L., Huang, C., Xie, L., Pack, A., Wörner, G., He, M., Li, C., Yuan, H., Huang, F., Li, Q., Yang, J., Li, X., Wu, F. (2021): Isotopic Compositions (Li‐B‐Si‐O‐Mg‐Sr‐Nd‐Hf‐Pb) and Fe2+/ΣFe Ratios of Three Synthetic Andesite Glass Reference Materials (ARM‐1, ARM‐2, ARM‐3). - Geostandards and Geoanalytical Research, 45, 4, 719-745.
https://doi.org/10.1111/ggr.12399

Cite as: https://gfzpublic.gfz-potsdam.de/pubman/item/item_5007412

Abstract

To expand the newly developed ARM glasses as reference materials for in situ microanalysis of isotope ratios and iron oxidation state by a variety of techniques such as SIMS, LA-MC-ICP-MS and EPMA, we report Li-B-Si-O-Mg-Sr-Nd-Hf-Pb isotope data and Fe2+/ΣFe ratios for these glasses. The data were mainly obtained by TIMS, MC-ICP-MS, IR-MS and wet-chemistry colorimetric techniques. The quality of these data was cross-checked by comparing different techniques or by comparing the results from different laboratories using the same technique. All three glasses appear to be homogeneous with respect to the investigated isotope ratios (except for B in ARM-3) and Fe2+/ΣFe ratios at the scale of sampling volume and level of the analytical precision of each technique. The homogeneity of Li-B-O-Nd-Pb isotope ratios at the microscale (30–120 μm) was estimated using LA-MC-ICP-MS and SIMS techniques. We also present new EPMA major element data obtained using three different instruments for the glasses. The determination of reference values for the major elements and their uncertainties at the 95% confidence level closely followed ISO guidelines and the Certification Protocol of the International Association of Geoanalysts. The ARM glasses may be particularly useful as reference materials for in situ isotope ratio analysis.