Skip to main content
SpringerLink
Log in

Emission Mössbauer spectroscopy of V2O5 doped with 57Co

  • Published:
Radiochemistry Aims and scope

Abstract

A Mössbauer study of V2O5 doped with carrier-free 57Co showed that the iron produced by the nuclear decay of cobalt can be stabilized in different forms depending on the temperature conditions of the sample treatment. Components of di- and trivalent iron were identified in the spectra of the V2O5 melt solidified under the conditions of slow cooling. After quenching the melt by immersing the crucible in mercury, a component with an isomer shift of -0.53(2) mm s−1, corresponding to the oxidation state of +5, appears in the spectrum.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Herren, M. and Gudel, H.U., Inorg. Chem., 1992, vol. 31, p. 3683.

    Article  CAS  Google Scholar 

  2. Brunold, T.C., Gudel, H.U., et al., J. Luminescence, 1996, vol. 65, p. 293.

    Article  Google Scholar 

  3. Dedushenko, S.K., Makhina, I.B., et al., Hyperfine Interact., 2004, vols. 156/157, p. 417.

    Article  CAS  Google Scholar 

  4. Kulikov, L.A., Perfiliev, Yu.D., and Kopelev, N.S., J. Phys. Chem. Solids, 1995, vol. 56, p. 1089.

    Article  CAS  Google Scholar 

  5. Dedushenko, S.K., Kholodkovskaya, L.N., et al., J. Alloys Compd., 1997, vols. 262–263, p. 78.

    Article  Google Scholar 

  6. Perfil’ev, Yu.D., Kulikov, L.A., and Yurchenko, A.Yu., Russ. J. Inorg. Chem., 2000, vol. 45, p. 1568.

    Google Scholar 

  7. Dedushenko, S.K. and Perfil’ev, Yu.D., Izv. Ross. Akad. Nauk, Ser. Fiz., 2001, vol. 65, p. 1039.

    CAS  Google Scholar 

  8. Shannon, R.D., Acta Crysallogr., Sect. A, 1976, vol. 32, p. 751.

    Article  Google Scholar 

  9. Buffa, B., Demazeau, G., et al., Fiz. Tverd. Tela, 1981, vol. 23, no. 8, p. 2262.

    Google Scholar 

  10. Handbuch der präparativen anorganischen Chemie, Brauer, G., Ed., Stuttgart: Enke, 1954. Translated under the title Rukovodstvo po neorganicheskomu sintezu, Moscow: Mir, 1985, vol. 5, p. 1524.

    Google Scholar 

  11. Menil, F., J. Phys. Chem. Solids, 1985, vol. 46, p. 763.

    Article  CAS  Google Scholar 

  12. Dedushenko, S.K., Perfil’ev, Yu.D., et al., in Trudy IV Mezhdunarodnoi konferentsii “Kristally: rost, svoistva, real’naya struktura, primenenie” (Proc. IV Int. Conf. “Crystals: Growth, Properties, Real Structure, and Applications”), Aleksandrov: VNIISIMS, 1999, vol. 2, p. 477.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Chemical Faculty, Lomonosov State University, Moscow, 119899, Russia

    S. K. Dedushenko, L. A. Kulikov & Yu. D. Perfil’ev

Authors
  1. S. K. Dedushenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. L. A. Kulikov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yu. D. Perfil’ev
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to S. K. Dedushenko.

Additional information

Original Russian Text © S.K. Dedushenko, L.A. Kulikov, Yu.D. Perfil’ev, 2014, published in Radiokhimiya, 2014, Vol. 56, No. 5, pp. 411–414.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Dedushenko, S.K., Kulikov, L.A. & Perfil’ev, Y.D. Emission Mössbauer spectroscopy of V2O5 doped with 57Co. Radiochemistry 56, 481–485 (2014). https://doi.org/10.1134/S106636221405004X

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S106636221405004X

Keywords

Search

Navigation